176690-90-7

Basic information

• Product Name: methyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-β-D-glucopyranoside
• Synonyms: methyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-β-D-glucopyranoside
• CAS NO: 176690-90-7
• Molecular Weight: 443.453
• Mol File: 176690-90-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: methyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-β-D-glucopyranoside(176690-90-7)
• EPA Substance Registry System: methyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-β-D-glucopyranoside(176690-90-7)

Safety Data

• Hazardous Substances Data: 176690-90-7(Hazardous Substances Data)

Upstream product

• 3055-46-7 methyl N-acetyl-D-glucosamine 
• 98-88-4 benzoyl chloride 
• 496065-66-8 methyl 2-acetamido-3-O-benzoyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside 
• 3068-34-6 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester 
• 3946-01-8 methyl N-acetyl-β-D-glucosaminide 

Downstream Products

• 1370587-63-5 methyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-β-D-xylo-hexapyranoside-4-ulose 
• 176690-92-9 methyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-4-O-trifluormethanesulfonyl-β-D-galactopyranoside 
• 176690-93-0 methyl 2-acetamido-4-S-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-3,6-di-O-benzoyl-2-deoxy-4-thio-β-D-glucopyranoside 
• 290819-66-8 methyl 2-acetamido-3,6-di-O-benzoyl-2,4-dideoxy-4-fluoro-β-D-glucopyranoside 
• 210472-45-0 methyl 2-acetamido-3,6-di-O-acetyl-2,4-dideoxy-4-fluoro-β-D-glucopyranoside 
• 176690-91-8 methyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-β-D-galactopyranoside 
• 269065-38-5 methyl 2-acetamido-3,6-di-O-benzoyl-2,4-dideoxy-β-D-xylo-hexopyranoside 

Relevant articles and documents

3- and 4-uloses derived from N-acetyl- D -glucosamine: A unique pair of complementary organocatalysts for asymmetric epoxidation of alkenes

The 4-ulose and the 3-ulose, both derived in two steps from the α-methyl glycoside of N-acetyl-D-glucosamine (GlcNAc), act as organocatalysts in the asymmetric epoxidation of alkenes, with unprecedented complementary enantioselectivity. The best results are found with α,β-unsaturated esters as substrates, with enantiomeric ratios up to 90:10 and 11:89, respectively. Copyright

Synthesis and conformational analysis of glycomimetic analogs of thiochitobiose

The synthesis of six analogs of N,N′-diacetylchitobiose is reported, including a novel transglycosylation reaction for the preparation of S-aryl thioglycosides. The conformations of the compounds were studied by a combination of NMR spectroscopy and molec

Synthesis of 4-deoxy-4-fluoro analogues of 2-acetamido-2-deoxy-D-glucose and 2-acetamido-2-deoxy-D-galactose and their effects on cellular glycosaminoglycan biosynthesis

4-Deoxy-4-fluoro analogues of 2-acetamido-2-deoxy-D-glucose and 2-acetamido-2-deoxy-D-galactose were synthesized and evaluated as inhibitors of hepatic glycosaminoglycan biosynthesis. 2-Acetamido-1,3,6-tri-O-acetyl-2,4-dideoxy-4-fluoro-D-glucopyranose (16) exhibited a reduction of [3H]GlcN and [35S]SO4 incorporation into hepatocyte cellular glycosaminoglycans to 12 and 18%, respectively, of the control cells, at 1.0 mM. Similarly, 2-acetamido-1,3,6-tri-O-acetyl-2,4-dideoxy-4-fluoro-D-galactopyranose (31) exhibited a reduction of [3H]GlcN and [35S]SO4 incorporation to 1 and 9%, respectively, of the control cells, at 1.0 mM. Unlike 16, 31 exhibited a reduction of [14C]Leu incorporation into cellular protein to 57% of control cells, at 1.0 mM. Copyright (C) 2000 Elsevier Science Ltd.