177084-19-4

Basic information

• Product Name: 4,5-dihydro-4,4-dimethyl-5-(2-methylallyl)-2-phenyl-1,3-thiazole-5-thiol
• Synonyms: 4,5-dihydro-4,4-dimethyl-5-(2-methylallyl)-2-phenyl-1,3-thiazole-5-thiol
• CAS NO: 177084-19-4
• Molecular Weight: 277.455
• Mol File: 177084-19-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4,5-dihydro-4,4-dimethyl-5-(2-methylallyl)-2-phenyl-1,3-thiazole-5-thiol(CAS DataBase Reference)
• NIST Chemistry Reference: 4,5-dihydro-4,4-dimethyl-5-(2-methylallyl)-2-phenyl-1,3-thiazole-5-thiol(177084-19-4)
• EPA Substance Registry System: 4,5-dihydro-4,4-dimethyl-5-(2-methylallyl)-2-phenyl-1,3-thiazole-5-thiol(177084-19-4)

Safety Data

• Hazardous Substances Data: 177084-19-4(Hazardous Substances Data)

Upstream product

• 81837-94-7 4,4-dimethyl-2-phenyl-1,3-thiazole-5(4H)-thione 
• 563-47-3 3-Chloro-2-methylpropene 
• 33324-92-4 (2-methylallyl)magnesium bromide 

Relevant articles and documents

34. New addition reactions of organometal compounds with 4,4-dimethyl-1,3-thiazole-5(4H)-thiones

Addition reactions of organometallic reagents with 4,4-disubstituted 1,3-thiazole-5(4H)-thiones were studied. Whereas the reactions with alkyllithium and alkyl Grignard reagents occurred in the thiophilic manner, the carbophilic addition was observed with allyllithium and allyl Grignard reagents. A radical reaction mechanism is proposed for rationalizing these observations (Scheme 5). A radical cyclization of the prepared 5-allyl-4,5-dihydro-1,3-thiazole-5-thiol derivatives yielded 1,6-dithia-3-azaspiro[4,4]non-2-enes (Table 4).