17734-25-7

Basic information

• Product Name: 7-phenyl-1-cyanoheptane
• Synonyms: 7-phenyl-1-cyanoheptane
• CAS NO: 17734-25-7
• Molecular Weight: 201.312
• Mol File: 17734-25-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 7-phenyl-1-cyanoheptane(CAS DataBase Reference)
• NIST Chemistry Reference: 7-phenyl-1-cyanoheptane(17734-25-7)
• EPA Substance Registry System: 7-phenyl-1-cyanoheptane(17734-25-7)

Safety Data

• Hazardous Substances Data: 17734-25-7(Hazardous Substances Data)

Upstream product

• 58654-08-3 7-iodoheptanenitrile 
• 100-39-0 benzyl bromide 
• 26447-64-3 1-phenyl-3-heptene 
• 75-86-5 2-hydroxy-2-methylpropanenitrile 
• 78573-85-0 1-bromo-7-phenyl-heptane 
• 3208-25-1 7-phenylheptan-1-ol 
• 151-50-8 potassium cyanide 

Downstream Products

• 128648-98-6 8-Phenyl-octanamidine 
• 17734-23-5 8--phenyloctan--1--amine 

Relevant articles and documents

Nickel-Catalyzed Migratory Hydrocyanation of Internal Alkenes: Unexpected Diastereomeric-Ligand-Controlled Regiodivergence

A regiodivergent nickel-catalyzed hydrocyanation of a broad range of internal alkenes involving a chain-walking process is reported. When appropriate diastereomeric biaryl diphosphite ligands are applied, the same starting materials can be converted to either linear or branched nitriles with good yields and high regioselectivities. DFT calculations suggested that the catalyst architecture determines the regioselectivity by modulating electronic and steric interactions. In addition, moderate enantioselectivities were observed when branched nitriles were produced.

Cross-Coupling between Functionalized Alkylcopper Reagents and Functionalyzed Alkyl Halides

Functionalized dialkylzincs treated with Me2Cu(CN)(MgCl)2 in DMPU undergo highly chemoselective cross-coupling reactions with functionalized alkyl iodides or benzylic bromides providing polyfunctional products in good to excellent yields.