177763-19-8

Basic information

• Product Name: (Z)-N-(2-(but-2-en-1-yl)phenyl)-4-methylbenzenesulfonamide
• Synonyms: (Z)-N-(2-(but-2-en-1-yl)phenyl)-4-methylbenzenesulfonamide
• CAS NO: 177763-19-8
• Molecular Weight: 301.409
• Mol File: 177763-19-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (Z)-N-(2-(but-2-en-1-yl)phenyl)-4-methylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-N-(2-(but-2-en-1-yl)phenyl)-4-methylbenzenesulfonamide(177763-19-8)
• EPA Substance Registry System: (Z)-N-(2-(but-2-en-1-yl)phenyl)-4-methylbenzenesulfonamide(177763-19-8)

Safety Data

• Hazardous Substances Data: 177763-19-8(Hazardous Substances Data)

Upstream product

• 243844-35-1 N-[2-(chloromethyl)-phenyl]-4-methylbenzene-1-sulfonamide 
• 118-92-3 anthranilic acid 
• 590-13-6 (Z)-1-propenyl bromide 
• 98-59-9 p-toluenesulfonyl chloride 
• 90312-02-0 N-(2-hydroxymethylphenyl)-4-methylbenzenesulfonamide 
• 13154-14-8 1-propenylmagnesium bromide 
• 5344-90-1 2-Aminobenzyl alcohol 
• 590-14-7 1-bromo-1-propene 

Relevant articles and documents

Pd(II)-catalyzed enantioselective intramolecular oxidative amination utilizing (+)-camphorsulfonic acid

An enantioselective Pd(II)-catalyzed intramolecular oxidative amination reaction was developed utilizing the commercially available chiral X-type ligand (1S)-(+)-camphorsulfonic acid. The Wacker-type cyclization produced chiral indoline products with enantioselectivies up to 45% ee. Electronic structure calculations employing density functional theory support a trans-aminopalladation mechanism.

Aerobic intramolecular oxidative amination of alkenes catalyzed by NHC-coordinated palladium complexes

Palladium(II) complexes bearing a single N-heterocyclic carbene ligand serve as effective catalysts for the aerobic oxidative cyclization of alkenes with pendant sulfonamides. The use of carboxylic acid cocatalysts (AcOH and PhCO2H) often leads