179260-96-9Relevant articles and documents
Total syntheses of (±)-musellarins A-C
Li, Zhilong,Leung, Tsz-Fai,Tong, Rongbiao
, p. 10990 - 10993 (2014)
The first, diastereoselective total syntheses of musellarins A-C were achieved concisely with 7.8-9.8% yields in 15-16 steps. The key synthetic features include (i) an Achmatowicz rearrangement, Kishi reduction, and Friedel-Crafts cyclization to construct
Asymmetric synthesis of fortucine and reassignment of its absolute configuration
Beaulieu, Marc-Andre,Ottenwaelder, Xavier,Canesi, Sylvain
supporting information, p. 7581 - 7584 (2014/07/07)
A convergent and enantioselective synthesis of fortucine was achieved from the starting materials tyrosine methyl ester and 3-hydroxy-4- methoxybenzaldehyde. The synthesis is based on two key steps mediated by a hypervalent iodine reagent. This work has enabled us to reassign the absolute configuration of the natural product reported in the literature. A multi-tool for total synthesis: A convergent and enantioselective synthesis of fortucine was achieved from the starting materials tyrosine methyl ester and 3-hydroxy-4-methoxybenzaldehyde. The synthesis is based on two key steps mediated by a 'multi-tool' hypervalent iodine reagent (see scheme).
