181297-82-5

Basic information

• Product Name: 2-[4-(TERT-BUTYL)PHENOXY]BENZENECARBALDEHYDE
• Synonyms: 2-[4-(TERT-BUTYL)PHENOXY]BENZENECARBALDEHYDE
• CAS NO: 181297-82-5
• Molecular Formula: C₁₇H₁₈O₂
• Molecular Weight: 254.32
• Mol File: 181297-82-5.mol
• Article Data: 7

Chemical Properties

• Melting Point: 46-48°C
• Boiling Point: 349.4±25.0 °C(Predicted)
• Appearance: /
• Density: 1.066±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 2-[4-(TERT-BUTYL)PHENOXY]BENZENECARBALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[4-(TERT-BUTYL)PHENOXY]BENZENECARBALDEHYDE(181297-82-5)
• EPA Substance Registry System: 2-[4-(TERT-BUTYL)PHENOXY]BENZENECARBALDEHYDE(181297-82-5)

Safety Data

• HazardClass: IRRITANT
• Hazardous Substances Data: 181297-82-5(Hazardous Substances Data)

Usage

Physical state

white solid substance

Common uses

synthesis of pharmaceuticals, agrochemicals, and other organic compounds
Role as a building block in organic material production
Utilized as a fragrance ingredient in perfumes and cosmetics
Studied for potential applications in polymer chemistry and material science.

Upstream product

• 98-54-4 para-tert-butylphenol 
• 446-52-6 2-Fluorobenzaldehyde 
• 84563-54-2 bis(4-tert-butylphenyl)iodonium trifluoromethanesulfonate 
• 71730-46-6 benzo[e][1,2,3]oxathiazine 2,2-dioxide 

Downstream Products

• 87-18-3 4-tert-butylphenyl salicylate 
• 917602-11-0 (5Z)-5-[2-(4-tert-butylphenoxy)benzylidene]-1,3-thiazolidine-2,4-dione 

Relevant articles and documents

Pyrimidine onium compound and application thereof

The invention relates to a pyrimidine onium compound, nitride oxides, salt of the nitride oxides and a composition comprising the compound. The invention further relates to an application of the compound to plant pest control.

Cross dehydrogenative coupling via base-promoted homolytic aromatic substitution (BHAS): Synthesis of fluorenones and xanthones

Cross dehydrogenative coupling reactions occurring via base-promoted homolytic aromatic substitutions (BHASs) are reported. Fluorenones and xanthones are readily prepared via CDC starting with readily available ortho-formyl biphenyls and ortho-formyl biphenylethers, respectively. The commercially available and cheap tBuOOH is used as an oxidant. Initiation of the radical chain reaction is best achieved with small amounts of FeCp2 (0.1 or 1 mol %).

An aryl to imidoyl palladium migration process involving intramolecular C-H activation

Biologically interesting fluoren-9-one and xanthen-9-one derivatives have been prepared by a novel aryl to imidoyl palladium migration, followed by intramolecular arylation. The fluoren-9-one synthesis appears to involve both a palladium migration mechanism and a C-H activation process proceeding through an unprecedented organopalladium(IV) hydride intermediate. The results from deuterium labeling experiments are consistent with the proposed dual mechanism.