18407-42-6

Basic information

• Product Name: Silane, (iodomethyl)methyldiphenyl-
• CAS NO: 18407-42-6
• Molecular Formula: C14H15ISi
• Molecular Weight: 338.263
• Mol File: 18407-42-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, (iodomethyl)methyldiphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (iodomethyl)methyldiphenyl-(18407-42-6)
• EPA Substance Registry System: Silane, (iodomethyl)methyldiphenyl-(18407-42-6)

Safety Data

• Hazardous Substances Data: 18407-42-6(Hazardous Substances Data)

Upstream product

• 18407-40-4 chloromethyl-methyl-diphenyl-silane 
• 67-64-1 acetone 

Downstream Products

• 110598-73-7 C₄₁H₄₆O₂Si₂ 
• 110598-73-7 C₄₁H₄₆O₂Si₂ 
• 110598-64-6 2-diphenylmethylsilylethylidenetris(4-methoxyphenyl)phosphorane 
• 110598-75-9 C₃₁H₄₂O₂Si₂ 
• 110598-75-9 C₃₁H₄₂O₂Si₂ 
• 110598-67-9 ((1R,2R)-2-Benzyloxy-4-phenyl-1-vinyl-butoxy)-methyl-diphenyl-silane 
• 110598-67-9 ((1R,2S)-2-Benzyloxy-4-phenyl-1-vinyl-butoxy)-methyl-diphenyl-silane 
• 110598-79-3 [(R)-1-((S)-Benzyloxy-cyclohexyl-methyl)-allyloxy]-methyl-diphenyl-silane 
• 110598-79-3 [(R)-1-((R)-Benzyloxy-cyclohexyl-methyl)-allyloxy]-methyl-diphenyl-silane 
• 110598-71-5 Acetic acid (1R,2R)-2-(methyl-diphenyl-silanyloxy)-1-phenethyl-but-3-enyl ester 
• 110598-71-5 Acetic acid (1S,2R)-2-(methyl-diphenyl-silanyloxy)-1-phenethyl-but-3-enyl ester 
• 110598-69-1 ((1R,2S)-2-Methoxy-4-phenyl-1-vinyl-butoxy)-methyl-diphenyl-silane 
• 110598-69-1 ((1R,2R)-2-Methoxy-4-phenyl-1-vinyl-butoxy)-methyl-diphenyl-silane 
• 110598-77-1 [(R)-1-((R)-1-Benzyloxy-ethyl)-allyloxy]-methyl-diphenyl-silane 

Relevant articles and documents

A highly diastereomerically enriched, silyl-substituted alkyl lithium, configurationally stable at room temperature

The opening or blocking of a coordination site at the lithium center (for example by attachment of THF, see picture; left) leads to diastereodivergent courses in the reactions of a highly diastereomerically enriched alkyl lithium with Me3SnCl. At room temperature in noncoordinating solvents the reagent is configurationally stable and epimerizes in the presence of THF. (Chemical Equation Presented)

Vinyl Anion Equivalent V. Asymmetric Synthesis of Allylic Alcohols Using Chiral 2-(Trialkylsilyl)ethyl Sulfoxides

Both enantiomers of optically pure secondary allylic alcohols can be conveniently prepared by the diastereoselective reaction of the α-sulfinyl carbanion of p-tolyl 2-(trialkylsilyl)ethyl sulfoxides or tert-butyl 2-(trimethylsilyl)ethyl sulfoxide with aldehydes followed by either fluoride-induced desilylsulfinylation or thermal elimination of the sulfinyl group.