18486-53-8

Basic information

• Product Name: methyl (methyl α,β-D-galactopyranosid)uronate
• CAS NO: 18486-53-8
• Molecular Weight: 222.195
• Mol File: 18486-53-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl (methyl α,β-D-galactopyranosid)uronate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (methyl α,β-D-galactopyranosid)uronate(18486-53-8)
• EPA Substance Registry System: methyl (methyl α,β-D-galactopyranosid)uronate(18486-53-8)

Safety Data

• Hazardous Substances Data: 18486-53-8(Hazardous Substances Data)

Upstream product

• 129530-46-7 1-O-methyl-2,3-O-isopropylidene-α-D-mannuronic acid methyl ester 
• 67-56-1 methanol 
• 643-33-4 D-galacturonic acid 
• 74-88-4 methyl iodide 
• 34234-44-1 methyl 2,3,4-tri-O-benzoyl-α-D-mannopyranoside 
• 34212-64-1 methyl 2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 617-04-9 (2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol 
• 77-76-9 2,2-dimethoxy-propane 
• 5391-16-2 methyl-α-D-mannopyranosideuronic acid 
• 88677-01-4 methyl (methyl 2,3,4-tri-O-benzyl-α-D-mannopyranosid)uronate 
• 7424-09-1 D-mannuronic acid-3-lactone 
• 1195221-20-5 O²,O³,O⁴-tribenzoyl-O¹-methyl-α-D-mannopyranuronic acid methyl ester 

Relevant articles and documents

Electroorganic synthesis 66: Selective anodic oxidation of carbohydrates mediated by TEMPO

The carbohydrates 4-15 are anodically oxidized with 2,2,6,6- tetramethylpiperidin-1-oxyl (TEMPO) as mediator. Selective and complete reaction at the primary hydroxyl groups affords the corresponding carboxylic acids 16-32 in moderate to excellent yield. Methyl α-D-glucopyranoside is converted in 98% yield to the uronic acid 16. Cyclic voltammetry shows that the oxydation is base-catalyzed and the oxidation of the hydroxy group with TEMPO+ (2) is rate determining.

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SYNTHESIS OF METHYL ETHERS OF URONIC ACIDS. III. SYNTHESIS OF METHYL (METHYL-α-D-MANNOPYRANOSID)URONATE AND ITS 2- AND 4-O-METHYL ETHERS

The synthesis of methyl (methyl α-D-mannopyranosid)uronate and its 2- and 4-O-methyl ethers has been effected by the chromium trioxide oxidation of the corredponding O-benzyl and O-benzylidene derivatives of methyl α-D-mannopyranoside, esterification with