18511-64-3Relevant articles and documents
Mild and efficient desulfurization of thiiranes with MoCl5/Zn system
Lee, Yeong Jin,Shin, Jeong Won,Yoo, Byung Woo
, (2021/11/10)
Desulfurization of a variety of thiiranes to alkenes occurs chemoselectively in high yields upon treatment with MoCl5/Zn system under mild conditions. The new methodology demonstrates high functional group tolerance toward chloro, bromo, fluoro, methoxy, ester, ether and keto groups.
Isolation of the key intermediates in the catalyst-free conversion of oxiranes to thiiranes in water at ambient temperature
Kleiner, Christian M.,Horst, Luise,Wuertele, Christian,Wende, Raffael,Schreiner, Peter R.
supporting information; experimental part, p. 1397 - 1403 (2009/12/04)
Herein we shed light on the mechanism of the reaction of epoxides with ammonium thiocyanate to give the corresponding thiiranes in water, and we present a computational mechanistic model for this highly useful reaction.
