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186255-41-4

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186255-41-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 186255-41-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,8,6,2,5 and 5 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 186255-41:
(8*1)+(7*8)+(6*6)+(5*2)+(4*5)+(3*5)+(2*4)+(1*1)=154
154 % 10 = 4
So 186255-41-4 is a valid CAS Registry Number.

186255-41-4Relevant articles and documents

SELECTIVE CARBON-CARBON BOND CLEAVAGE BY EARTH ABUNDANT VANADIUM COMPOUNDS UNDER VISIBLE LIGHT PHOTOCATALYSIS

-

, (2016/09/22)

Provided herein a vanadium(V) complex of formula I, where R1 to R8 are as defined herein. Also provided herein are reactions making use of the vanadium(V) complex of formula I, such as selective sp3-sp3 carbon-carbon bond cleavage under visible light photocatalysis and photodegradation of lignin.

Non-oxidative vanadium-catalyzed co bond cleavage: Application to degradation of lignin model compounds

Son, Sunghee,Toste, F. Dean

supporting information; experimental part, p. 3791 - 3794 (2010/08/22)

(Chemical Equation Presented) New direction: Changes In the ligand structure divert the reactivity of vanadium (V) oxo complexes from alcohol oxidation to a novel non-oxidative C-O bond cleavage. Thus, highly functionalized aryl enones can be selectively generated from lignin model compounds by vanadium-catalyzed cleavage of the β-O-4 linkage (see scheme; N blue, O red).

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