188303-62-0

Basic information

• Product Name: (4S,5S)-2-Ethoxy-4,5-bis-(3-methoxy-benzyloxymethyl)-2-vinyl-[1,3]dioxolane
• CAS NO: 188303-62-0
• Molecular Weight: 444.525
• Mol File: 188303-62-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4S,5S)-2-Ethoxy-4,5-bis-(3-methoxy-benzyloxymethyl)-2-vinyl-[1,3]dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,5S)-2-Ethoxy-4,5-bis-(3-methoxy-benzyloxymethyl)-2-vinyl-[1,3]dioxolane(188303-62-0)
• EPA Substance Registry System: (4S,5S)-2-Ethoxy-4,5-bis-(3-methoxy-benzyloxymethyl)-2-vinyl-[1,3]dioxolane(188303-62-0)

Safety Data

• Hazardous Substances Data: 188303-62-0(Hazardous Substances Data)

Upstream product

• 188303-55-1 (4S,5S)-4,5-Bis-(3-methoxy-benzyloxymethyl)-2,2-dimethyl-[1,3]dioxolane 
• 824-98-6 m-methoxybenzyl chloride 
• 42216-96-6 triethyl orthoacrylate 
• 188303-51-7 (2S,3S)-1,4-Bis-(3-methoxy-benzyloxy)-butane-2,3-diol 

Relevant articles and documents

2-Alkenyl dioxolanylium cations, new reactive dienophiles in low temperature asymmetric Diels-Alder reactions

Chiral orthoesters 14-22 were prepared by an exchange reaction with orthoester 13. These compounds, after treatment with trimethylsilyltriflate or tin(IV) chloride, gave rise to vinyl dioxolanylium cations which proved to be very reactive dienophils in various Diels-Alder reactions.