19287-65-1

Basic information

• Product Name: 9H-Carbazole, 9-(3-nitrophenyl)-
• CAS NO: 19287-65-1
• Molecular Formula: C18H12N2O2
• Molecular Weight: 288.305
• Mol File: 19287-65-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 9H-Carbazole, 9-(3-nitrophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 9H-Carbazole, 9-(3-nitrophenyl)-(19287-65-1)
• EPA Substance Registry System: 9H-Carbazole, 9-(3-nitrophenyl)-(19287-65-1)

Safety Data

• Hazardous Substances Data: 19287-65-1(Hazardous Substances Data)

Upstream product

• 13029-09-9 2,2'-dibromobiphenyl 
• 99-09-2 3-nitro-aniline 
• 13029-08-8 2,2'-Dichlorobiphenyl 
• 2236-52-4 2,2'-diiodobiphenyl 
• 696-59-3 cis,trans-2,5-dimethoxytetrahydrofuran 
• 4310-42-3 1-(3-nitrophenyl)-1H-pyrazole 
• 2113-51-1 2-iodobiphenyl 
• 189999-35-7 [1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate 

Relevant articles and documents

A tuned bicyclic proazaphosphatrane for catalytically enhanced n-arylation reactions with aryl chlorides

The N-arylation of various amines with aryl chlorides proceeded in good-to-excellent yields in the presence of P[N{(p-NMe2)C6H4CH2}CH2CH2]3N (1e, a new electron-rich proazaphosphatrane ligand) and small amounts of Pd2(dba)3 (dba = dibenzylideneacetone). This catalytic system was also very effective for the synthesis of carbazoles. An efficient palladium-catalyzed N-arylation reaction of amines under mild conditions with a tuned bicyclic proazaphosphatrane has been developed.

Palladium-catalyzed synthesis of N-arylated carbazoles using anilines and cyclic diaryliodonium salts

The direct synthesis of N-arylated carbazoles through a palladium-catalyzed amination of cyclic iodonium salts with anilines is described. In particular, electron-poor aniline derivatives reacted smoothly with only 5 mol % of Pd(OAc)2 as catalyst to give the desired products in up to 71% yield. Furthermore, the reactivity of cyclic iodonium salts is compared with the reactivity of the corresponding cyclic bromonium analogues.