19433-13-7

Basic information

• Product Name: Benzaldehyde, O-acetyloxime
• CAS NO: 19433-13-7
• Molecular Formula: C9H9NO2
• Molecular Weight: 163.176
• Mol File: 19433-13-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, O-acetyloxime(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, O-acetyloxime(19433-13-7)
• EPA Substance Registry System: Benzaldehyde, O-acetyloxime(19433-13-7)

Safety Data

• Hazardous Substances Data: 19433-13-7(Hazardous Substances Data)

Upstream product

• 75-36-5 acetyl chloride 
• 932-90-1 Benzaldoxime 
• 932-90-1 syn-benzaldehyde oxime 
• 108-24-7 acetic anhydride 
• 119-61-9 benzophenone 
• 80055-49-8 (E)-benzaldehyde O-acetyl oxime 
• 7726-95-6 bromine 
• 7647-01-0 hydrogenchloride 
• 622-32-2 (Z)-benzaldehyde oxime 
• 830-03-5 4-nitrophenol acetate 
• 108-05-4 vinyl acetate 
• 100-52-7 benzaldehyde 

Downstream Products

• 100-47-0 benzonitrile 
• 2227-79-4 benzenecarbothioamide 
• 622-32-2 (Z)-benzaldehyde oxime 
• 64-19-7 acetic acid 
• 833-50-1 2-phenylbenzo[d]oxazole 
• 71255-64-6 C₉H₁₁NO₂ 

Relevant articles and documents

Acylation and alkoxycarbonylation of oximes through an enzymatic oximolysis reaction

Ketone or benzaldehyde O-acyloximes and O-(tert-butoxycarbonyl)oximes can be prepared by reaction of oximes with vinyl esters and di-tert-butyl dicarbonate, respectively, using lipases as biocatalysts.

Initiators based on benzaldoximes: Bimolecular and covalently bound systems

Typical bimolecular photoinitiators (PIs) for radical polymerization of acrylates show only poor photoreactivity because of the undesired effect of back electron transfer. To overcome this limitation, PIs consisting of a benzaldoxime ester and various sensitizers based on aromatic ketones were introduced. The core of the photoinduced reactivity was established by laser flash photolysis, photo-CIDNP, and EPR experiments at short time scales. According to these results, the primarily formed iminyl radicals are not particularly active. The polymerization is predominantly initiated by C-centered radicals. Photo-DSC experiments show reactivities comparable to that of classical monomolecular type I PIs like Darocur 1173.

EFFETS MICELLAIRES SUR LA BASICITE ET LA REACTIVITE DE NUCLEOPHILES α AROMATIQUES

The oximation of p-nitrophenylacetate by benzaldoximates in aqueous solution is catalyzed by CTAB micelles.The catalysis is more effective when the base strength of the oximate decreases; the reactivity of benzaldoximates is not dependent on their basicity.Our data may be interpreted in terms of orbital-controlled reactions, with interactions between both the n and ? occupied orbitals of the oximates and the LUMO of the acetate.