194869-04-0

Basic information

• Product Name: Benzenamine, 2-[[tris(1-methylethyl)silyl]oxy]-
• CAS NO: 194869-04-0
• Molecular Formula: C15H27NOSi
• Molecular Weight: 265.471
• Mol File: 194869-04-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenamine, 2-[[tris(1-methylethyl)silyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 2-[[tris(1-methylethyl)silyl]oxy]-(194869-04-0)
• EPA Substance Registry System: Benzenamine, 2-[[tris(1-methylethyl)silyl]oxy]-(194869-04-0)

Safety Data

• Hazardous Substances Data: 194869-04-0(Hazardous Substances Data)

Upstream product

• 13154-24-0 triisopropylsilyl chloride 
• 95-55-6 2-amino-phenol 

Downstream Products

• 194869-12-0 tert-butyl 2-((triisopropylsilyl)oxy)phenylcarbamate 
• 863312-49-6 2-(2-triisopropylsilanyloxy-phenylamino)-cyclohex-2-enone 
• 863312-38-3 (6-oxo-cyclohex-1-enyl)-(2-triisopropylsilanyloxy-phenyl)-carbamic acid methyl ester 
• 863312-50-9 trifluoro-methanesulfonic acid 6-[methoxycarbonyl-(2-triisopropylsilanyloxy-phenyl)-amino]-cyclohexa-1,5-dienyl ester 
• 863312-39-4 [6-(2-tert-butoxycarbonylamino-ethyl)-cyclohexa-1,5-dienyl]-(2-triisopropylsilanyloxy-phenyl)-carbamic acid methyl ester 
• 398136-58-8 tert-butyl 2-[(triisopropylsilyl)oxy]-6-(trimethylsilyl)phenylcarbamate 
• 398136-41-9 tert-butyl 2-(4-methoxybenzyl)-6-[(triisopropylsilyl)oxy]phenylcarbamate 
• 398136-54-4 4-(4-methoxybenzyl)-1,3-benzoxazol-2(3H)-one 
• 398136-62-4 3-acryloyl-4-(4-methoxybenzyl)-1,3-benzoxazol-2(3H)-one 
• 194869-17-5 (2-Iodo-6-triisopropylsilanyloxy-phenyl)-carbamic acid tert-butyl ester 
• 194869-23-3 (2-Triisopropylsilanyloxy-6-trimethylsilanylethynyl-phenyl)-carbamic acid tert-butyl ester 
• 1229443-17-7 2-nitro-N-(2-(triisopropylsilyloxy)phenyl)benzenesulfonamide 
• 1245624-77-4 C₃₉H₅₅NO₃Si₂ 
• 900811-77-0 3-phenyl-3-hydroxy-1,3-dihydro-indol-2-one 

Relevant articles and documents

A facile pathway to enantiomerically enriched 3-hydroxy-2-oxindoles: Asymmetric intramolecular arylation of α-keto amides catalyzed by a palladium-DifluorPhos complex

Less metal wastes: The first catalytic, enantioselective intramolecular aryl-transfer reaction of aryl triflates to ketones has been developed (see scheme; R1=R2=aromatic and aliphatic). This method features overall practicality, inc

A mild deprotection of trichloroethyl carbamates using indium metal

The trichloroethoxycarbonyl moiety was efficiently removed from carbamates to furnish the corresponding amines using indium metal in good to excellent yields.

General and facile synthesis of indoles with oxygen-bearing substituents at the benzene moiety

Indoles with oxygen-bearing substituents such as a methoxy or (triisopropylsilyl)oxy group at all of the positions of the benzene moiety were synthesized by cyclization of tert-butyl methoxy(or (triisopropylsilyl)oxy)-2-((trimethylsilyl)ethynyl)phenyl)carbamates with potassium tert-butoxide in tert-butyl alcohol. The (ethynylphenyl)carbamates were synthesized by the palladium-catalyzed reaction of (trimethylsilyl)acetylene and the corresponding (iodophenyl)carbamates, which were selectively synthesized by directed lithiation of the phenylcarbamates and subsequent iodination.