19549-58-7Relevant articles and documents
The First Hydrides of a Phosphorus Sulfide Cage: Nuclear Magnetic Resonance Evidence for α-Tetraphosphorus Trisulfide Hydride Compounds
Tattershall, Bruce W.,Kendall, Nigel L.
, p. 3163 - 3168 (2007/10/02)
The hydrides α-P4S4(H)R (R = H, I, NMePh or SPh) have been prepared in solution by the reaction of α-P4S3I2 or of the corresponding α-P4S3(I)R with Sn-n-Bu3H, and identified by 31P NMR spectroscopy.The compounds were unstable and not isolated.Ab initio molecular orbital calculations of geometry have been carried out for α-P4S3H2, α-P4S3(NMe2)2 and α-P4S3H(NMe2).
