19991-69-6Relevant articles and documents
Effect of ester side chains on photovoltaic performance in thiophene-thiazolothiazole copolymers
Yamanaka, Kodai,Saito, Masahiko,Mikie, Tsubasa,Osaka, Itaru
, p. 2019 - 2027 (2021/09/16)
Thiazolothiazole-based π-conjugated polymers are promising semiconducting materials in organic photovoltaics (OPV). A series of thiophene-thiazolothiazole based polymers having ester side chains, PTzBTE and PTzBTEE was synthesized. A new synthetic methodology for their common monomer having ester group, in which the total yield was significantly improved by a factor of ten compared to the previous methodology. This led to polymer samples with high molecular weights. OPV cells using PTzBTE, in combination with [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM), demonstrated high efficiencies of as high as 8.9% despite its limited absorption range. This value is significantly higher than that for PTzBT having only alkyl groups as the side chain and that obtained for a low-molecular weight PTzBTEE sample reported previously. Meanwhile, although PTzBTEE had a well-ordered structure like PTzBTE, it showed lower OPV performances. Investigations of electronic properties and structural order and morphology in thin films were performed. The OPV cells fabricated with a nonhalogenated solvent showed efficiencies comparable to the cells fabricated by a conventional halogenated solvent.
Azacycle diketone compound and preparation method thereof (by machine translation)
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Paragraph 0648-0654, (2020/09/12)
The invention provides a azacyclodiketone compound which is characterized by being a compound represented by the following structure. The compound has inhibitory activity on cap-dependent endonuclease. (by machine translation)
Phosphorylamides, their preparation and use
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, (2008/06/13)
A phosphorylamide derivative represented by the general formula (I): STR1 wherein R represents an amino group that may be substituted, or a salt thereof, possesses potent antibacterial activity against Helicobacter bacterium, especially Helicobacter pylori, and is useful for prevention or treatment of digestive diseases caused by Helicobacter bacterium, solely or in combination with an antacid or an acid secretion inhibitor.