201477-90-9

Basic information

• Product Name: 1,4-bis((E)-(2S)-2-(tosyloxy)-4-decen-1-yloxy)benzene
• Synonyms: 1,4-bis((E)-(2S)-2-(tosyloxy)-4-decen-1-yloxy)benzene
• CAS NO: 201477-90-9
• Molecular Weight: 726.996
• Mol File: 201477-90-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,4-bis((E)-(2S)-2-(tosyloxy)-4-decen-1-yloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-bis((E)-(2S)-2-(tosyloxy)-4-decen-1-yloxy)benzene(201477-90-9)
• EPA Substance Registry System: 1,4-bis((E)-(2S)-2-(tosyloxy)-4-decen-1-yloxy)benzene(201477-90-9)

Safety Data

• Hazardous Substances Data: 201477-90-9(Hazardous Substances Data)

Upstream product

• 2232-08-8 N-tosylimidazole 
• 201477-87-4 (E)-(S)-1-[4-((E)-(S)-2-Hydroxy-dec-4-enyloxy)-phenoxy]-dec-4-en-2-ol 
• 201477-84-1 (S)-1-[4-((S)-2-Hydroxy-dec-4-ynyloxy)-phenoxy]-dec-4-yn-2-ol 
• 1027210-55-4 Acetic acid (R)-2-[4-((R)-2-acetoxy-3-bromo-propoxy)-phenoxy]-1-bromomethyl-ethyl ester 
• 201477-75-0 1,4-bis-(2-(S)-oxiranylmethoxy)benzene 
• 178237-88-2 (S)-3-[4-((S)-2,3-Dihydroxy-propoxy)-phenoxy]-propane-1,2-diol 
• 123-31-9 hydroquinone 
• 37592-20-4 1,4-bis(allyloxy)benzene 

Downstream Products

• 201477-97-6 1,4-bis((2R,4S,5S)-2,5-epoxy-4-[(tert-butyldimethylsilyl)oxy]dec-1-yloxy)benzene 
• 1054624-54-2 1,4-bis((2R,4S,5S)-2,5-epoxy-4-hydroxydec-1-yloxy)benzene 

Relevant articles and documents

Enantiocontrolled Construction of Functionalized Tetrahydrofurans: Total Synthesis of (6S,7S,9R,10R)-6,9-Epoxynonadec-18-ene-7,10-diol, a Marine Natural Product

An efficient strategy has been developed for the construction of highly functionalized tetrahydrofurans. The key feature involves the use of Sharpless asymmetric dihydroxylation and the choice of a new bis-C3 building block 5 as the starting material which increased the efficiency. On the basis of this methodology, a marine natural product, (6S,7S,9R,10R)-6,9-epoxynonadec-18-ene-7,10-diol (1), was successfully synthesized in high enantioselectivity.