201803-61-4

Basic information

• Product Name: C₂₄H₂₈O₂Si
• Synonyms: C₂₄H₂₈O₂Si
• CAS NO: 201803-61-4
• Molecular Weight: 376.571
• Mol File: 201803-61-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₄H₂₈O₂Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₄H₂₈O₂Si(201803-61-4)
• EPA Substance Registry System: C₂₄H₂₈O₂Si(201803-61-4)

Safety Data

• Hazardous Substances Data: 201803-61-4(Hazardous Substances Data)

Upstream product

• 33729-92-9 tert-butyldiphenylsilane 
• 105-13-5 4-Methoxybenzyl alcohol 

Downstream Products

• 105-13-5 4-Methoxybenzyl alcohol 

Relevant articles and documents

Potassium tert-butoxide-catalyzed dehydrogenative Si-O coupling: Reactivity pattern and mechanism of an underappreciated alcohol protection

A remarkable fen-butoxide-catalyzed coupling of alcohols and silanes is reported. Dihydrogen and not hydrochloric acid (generated in the prevalent, related coupling of alcohols and chlorosilanes) is formed as the sole by-product. A comprehensive survey of common silanes provides a reliable tool for the predictability of their reactivity under defined reaction conditions. The debated mechanism of this transformation is investigated monitoring the stereochemical course at the silicon atom by means of a silicon-stereogenic silane. On this basis, a transition state for the enantiospecific Si-O coupling step is suggested rationalizing the observed frontside attack and thus retention at the silicon atom.