206278-57-1

Basic information

• Product Name: (Z)-2,2-Dimethyl-4-phenylsulfanyl-non-4-en-3-one
• Synonyms: (Z)-2,2-Dimethyl-4-phenylsulfanyl-non-4-en-3-one
• CAS NO: 206278-57-1
• Molecular Weight: 276.443
• Mol File: 206278-57-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-2,2-Dimethyl-4-phenylsulfanyl-non-4-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2,2-Dimethyl-4-phenylsulfanyl-non-4-en-3-one(206278-57-1)
• EPA Substance Registry System: (Z)-2,2-Dimethyl-4-phenylsulfanyl-non-4-en-3-one(206278-57-1)

Safety Data

• Hazardous Substances Data: 206278-57-1(Hazardous Substances Data)

Upstream product

• 64214-60-4 N-methoxy-N-methylpivalamide 
• 13307-75-0 (phenylthio)methyllithium 
• 3282-30-2 pivaloyl chloride 
• 137782-88-8 (E)-1-phenylsulfanyl-1-tributylstannyl-1-hexene 
• 110-62-3 pentanal 
• 37471-41-3 3,3-dimethyl-1-(phenylthio)butan-2-one 

Relevant articles and documents

Enantioselective synthesis of α-hydroxy thioesters via oxazaborolidine- mediated reduction of α-phenylthio enones

α-Phenylthio-α,β-alkenones (2), readily available by Pd(II)-catalysed coupling of (E)-1 phenylthio-1-tributylstannylhex-1-ene with the corresponding acid chlorides have been treated with borane in the presence of phenylglycine- or proline-derived oxazaborolidines to afford 2-phenylthio-2- alken-1-ols (3) with good to excellent enantioselectivities. Ozonolysis of 3 provides a new and efficient route to chiral α-hydroxy thioesters 4.