20752-34-5Relevant articles and documents
Solodar
, p. 3461,3462-3464 (1976)
Pt/H-beta zeolites as productive bifunctional catalysts for the one-step citronellal-to-menthol conversion
Mertens, Pascal,Verpoort, Francis,Parvulescu, Andrei-Nicolae,De Vos, Dirk
, p. 7 - 13 (2006)
Pt-loaded H-beta zeolite was identified as a highly active catalyst for the bifunctional transformation of citronellal to menthol, with isopulegol as the intermediate. With a 2 wt% Pt-loaded catalyst, citronellal is fully converted within 12 h, with only 2.5 wt% catalyst with respect to citronellal, and with a citronellal to Pt molar ratio of 2500. 1, 4-Dioxane is the best reaction solvent, because it minimizes the unwanted direct hydrogenation of citronellal and promotes its stereoselective cyclization to isopulegol, leading to high menthol yields. The stereoselectivity can be improved moderately by using a Zr-impregnated support and more substantially by performing high-temperature (750 °C) treatment of the calcined and reduced catalyst. This treatment presumably creates extra Lewis acidity on the catalyst and results in 88% stereoselectivity for the desired menthol. Overall, an 85% yield of (-)-menthol was obtained.
Continuous flow synthesis of menthol: Via tandem cyclisation-hydrogenation of citronellal catalysed by scrap catalytic converters
Zuliani, Alessio,Cova, Camilla Maria,Manno, Roberta,Sebastian, Victor,Romero, Antonio A.,Luque, Rafael
, p. 379 - 387 (2020/02/13)
A continuous flow synthesis of menthol starting from citronellal catalysed by scrap catalytic converters is reported. The reaction was conducted in a tandem system connecting in series two catalytic systems, with the first having Lewis acid properties (favouring the cyclisation of citronellal to isopulegols) and the second having hydrogenation catalytic activity (catalysing the hydrogenation of isopulegols to menthols). A Lewis acid catalyst was prepared by supporting iron oxide nanoparticles over a waste material, i.e. the ceramic core of scrap catalytic converters (SCATs) via a microwave assisted method. Most importantly, SCATs, containing a low residual noble metal content, could be directly employed in the second step as hydrogenation catalysts. The reaction was performed studying the influence on the yield and selectivity to (-)-menthol of various reaction parameters (T, p and flow rate). Under the best reaction conditions (at a flow rate of 0.1 mL min-1 and at 373 K and 413 K for cyclisation and hydrogenation steps respectively) a conversion of >99% of (+)-citronellal to (-)-menthol with 77% final yield was achieved.
BENZO[H]QUINOLINE LIGANDS AND COMPLEXES THEREOF
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Page/Page column 73-75, (2016/12/22)
The present invention provides substituted tridentate benzo[h]quinoline ligands and complexes thereof. The invention also provides the preparation of the ligands and the respective complexes, as well as to processes for using the complexes in catalytic reactions.
