20799-74-0Relevant articles and documents
Strong and Selective Halide Anion Binding by Neutral Halogen-Bonding [2]Rotaxanes in Wet Organic Solvents
Lim, Jason Y. C.,Bunchuay, Thanthapatra,Beer, Paul D.
, p. 4700 - 4707 (2017)
The design and construction of neutral interlocked host molecules for anion recognition are rare. Using an active-metal template approach, the preparation of a family of neutral halogen bonding (XB) rotaxanes containing two, three and four iodotriazole groups integrated into the macrocycle and axle components is achieved. In spite of the interlocked hosts’ neutrality, such rotaxane systems are capable of binding halide anions strongly and selectively in wet organic solvent mixtures. Importantly, halide-binding strength and selectivity can be modulated by varying the number and position of the halogen bond donor iodotriazole groups within the interlocked cavity; the rotaxane containing the largest number of halogen bond donor groups exhibits the highest halide anion-binding affinities. By varying the percentage of water content in the solvent, neutral XB donor-mediated anion-binding strength is also demonstrated to be highly sensitive to solvent polarity.
Gold-catalyzed hydroarylating cyclization of 1,2-Bis(2-iodoethynyl)benzenes
N?sel, Pascal,Müller, Vanessa,Mader, Steffen,Moghimi, Setareh,Rudolph, Matthias,Braun, Ingo,Rominger, Frank,Hashmi, A. Stephen K.
supporting information, p. 500 - 506 (2015/03/05)
1,5-Diynes bearing halogen-substituted alkynes were synthesized and converted in the presence of a gold catalyst. In contrast to the corresponding hydroarylating aromatization reaction with terminal alkynes, a totally different reaction mode was observed.
Fusing triazoles: Toward extending aromaticity
Juricek, Michal,Stout, Kathleen,Kouwer, Paul H. J.,Rowan, Alan E.
, p. 3494 - 3497 (2011/09/14)
A novel method to extend aromaticity by one benzene and two triazole rings was developed and optimized. This two-step route employs the copper-catalyzed azide-haloalkyne cycloaddition reaction of an ortho-bis(iodoacetylene) system and the subsequent intra