20994-26-7Relevant articles and documents
Synthesis and characterization of block copolymers of polystyrene and thermotropic liquid crystalline polyesters
Chen, Cheng-Chih,Lin, Chih-Hung
, p. 125 - 133 (2018)
A series of block copolymers containing a thermotropic liquid crystalline polymer and an amorphous polystyrene have been synthesized. The block copolymers were prepared by solution polycondensation of α,ω-dicarboxylic acid-terminated polystyrene with 4,4′-dicarboxy-1,6-diphenoxy-hexane and 4,4′-bis(2-hydroxyalkyloxy)biphenyls in a mixture of triphenylphosphine, hexachloroethane, and pyridine. The obtained polymers were fractionated to isolate the pure block copolymer. The block copolymers were characterized by FTIR spectroscopy, differential scanning calorimetry, thermogravimetric analysis, optical polarizing microscopy measurement. Optical polarizing microscopy measurements verify the presence of a smectic liquid crystalline phase for the block copolymers. The block copolymers represent a microphase-separated morphology, i.e., both amorphous and liquid crystalline properties were displayed by the polystyrene and liquid crystalline polyester segments respectively.
One-pot synthesis of cyclophane-type macrocycles using manganese(iii)- mediated oxidative radical cyclization
Ito, Yosuke,Tomiyasu, Yuichi,Kawanabe, Takahiro,Uemura, Keisuke,Ushimizu, Yuu,Nishino, Hiroshi
supporting information; scheme or table, p. 1491 - 1507 (2011/04/23)
Cyclophane-type macrocyclic compounds from 21 to 56 members having two fused dihydrofuran rings were synthesized by the manganese(iii)-mediated oxidation of terminal dienes with bis(3-oxobutanoate)s containing aromatics. The reaction detail, characterization and reaction pathways are described. The Royal Society of Chemistry 2011.
Esters of 3-tert-butyl- and 3-tert-butyl-5-alkyl-4-hydroxyphenyl (alkane) carboxylic acids with oxethylates of polyhydroxyaromatics, process for their production, and their use as stabilizers
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, (2008/06/13)
Esters of 3-tert-butyl- and 3-tert-butyl-5-alkyl-4-hydroxyphenyl(alkane) carboxylic acids of Formula I STR1 with oxethylates of polyhydroxyaromatics of 2-6 hydroxy groups of general Formulae II and III, containing 1-6 oxethylate units, STR2 with X=(CH2)q OH X'=(CH2)r OH wherein q, r, s can be 0 or 1, preferably 0, X"=(CH2)s OH R,R', R"=H, alkyl, halogen, STR3 preferably 4-hydroxyphenyl, n=2 to 6 for z or z'=0, preferably 2 or 3, and n=1 to 5 for z or z'≠0, preferably 2 or 3, o+p=n 0≤a, z≤a+z≤6-n (in Formula II) 0≤b, c, z'≤4≤8-n (in Formula III). are useful for the stabilization of polymers.