216981-11-2

Basic information

• Product Name: (O(2,4,6-tris((dimethylamino)methyl)phenyl))2SnPt(PPh₃)2
• CAS NO: 216981-11-2
• Molecular Weight: 1367.15
• Mol File: 216981-11-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (O(2,4,6-tris((dimethylamino)methyl)phenyl))2SnPt(PPh₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: (O(2,4,6-tris((dimethylamino)methyl)phenyl))2SnPt(PPh₃)2(216981-11-2)
• EPA Substance Registry System: (O(2,4,6-tris((dimethylamino)methyl)phenyl))2SnPt(PPh₃)2(216981-11-2)

Safety Data

• Hazardous Substances Data: 216981-11-2(Hazardous Substances Data)

Upstream product

• 12120-15-9 ethylenebis(triphenylphosphine)platinum⁽⁰⁾ 
• 524960-14-3 bis[2,4,6-tris(dimethylaminomethyl)phenoxy]-stannylene 

Relevant articles and documents

Low coordinate germanium and tin compounds (ArO)2M=E and (ArO)2M=M′Ln M=Ge, Sn; E=S, Se, -NSiMe3 M′=Cr, W, Fe, Pt [Ar=2,4,6-tris((dimethylamino)methyl)phenyl-]

The reactions of the divalent species (ArO)2M (Ar=2,4,6-[(CH3)2NCH2]3C 6H2; M=Ge, Sn) with either Me3SiN3, elemental S8, Se or transition metal complexes M′(CO)n+1 (M′=Fe, n=4; M′=Cr, W; n=5) (Ph3P)2Pt·C2H4 have resulted in the isolation of either the new stable formal metallanimines (ArO)2M=N-SiMe3, germanethione, -selone (ArO)2Ge=E (E=S, Se) (the expected formations of the stannanethione and -selone were not observed), or the (ArO)2M=M′(CO)n, (ArO)2M=Pt(PPh3)2 complexes, respectively. The direct oxidation of the (ArO)2M species with various oxidizing agents led to the formation of the corresponding metalloxanes [(ArO)2M-O-]2. All of the chalcogenido- and transition metal-metal 14 complexes have been physicochemically and chemically characterized. The reactions of the (ArO)2Ge=E (E=S, Se) compounds with 3,5-di-tert-butyl-1,2-benzoquinone produced, by extrusion of sulfur or selenium, the dioxametalloles corresponding to the formal addition of the divalent species (ArO)2M to the benzoquinone. A substitution reaction of chalcogen (S/Se) has been observed permitting to go from germaneselone to germanethione.