221699-65-6Relevant articles and documents
Stereochemical course of the hydrogen migration in the boron trifluoride etherate-catalyzed rearrangement of 1,1-disubstituted epoxides
Hara, Noriyuki,Mochizuki, Akiyoshi,Tatara, Akinori,Fujimoto, Yoshinori
, p. 1859 - 1868 (2000)
Mechanistic studies on the BF3.Et2O-catalyzed rearrangement of optically active, regioselectively deuterated 1,1-disubstituted epoxides to aldehydic products revealed that the two hydrogens migrate at the migration terminus with oppo