22348-47-6

Basic information

• Product Name: 4-Hepten-1-ol, 7-phenyl-, (4E)-
• CAS NO: 22348-47-6
• Molecular Formula: C13H18O
• Molecular Weight: 190.285
• Mol File: 22348-47-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 4-Hepten-1-ol, 7-phenyl-, (4E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Hepten-1-ol, 7-phenyl-, (4E)-(22348-47-6)
• EPA Substance Registry System: 4-Hepten-1-ol, 7-phenyl-, (4E)-(22348-47-6)

Safety Data

• Hazardous Substances Data: 22348-47-6(Hazardous Substances Data)

Upstream product

• 120756-20-9 (E)-Ethyl 7-phenyl-4-heptenoate 
• 1027473-57-9 Methanesulfonic acid (E)-5-phenyl-pent-2-enyl ester 
• 344360-07-2 dimethyl 3-(2-phenylethyl)-2-propenylmalonate 
• 55282-95-6 ethyl (2E)-5-phenylpent-2-enoate 
• 75553-23-0 (E)-5-phenyl-2-penten-1-ol 
• 122-97-4 3-Phenyl-1-propanol 
• 104-53-0 3-phenyl-propionaldehyde 
• 344359-71-3 methyl 7-phenylhept-4-enoate 
• 5631-95-8 2,3-dichlorotetrahydro-2H-pyran 
• 103-63-9 1-phenyl-2-bromoethane 
• 100607-52-1 3-chloro-2-phenethyl-tetrahydro-pyran 

Downstream Products

• 100614-21-9 (E) 1-chloro-7-phenylhept-4-ene 
• 100613-86-3 7-bromo-1-phenyl-hept-3t-ene 
• 100532-93-2 7-phenyl-heptane-1,3,4-triol 
• 1217274-53-7 C₁₄H₂₀O₂ 
• 3208-40-0 2-(3-phenylprop-1-yl)-tetrahydrofuran 
• 1613582-56-1 (2S,6R)-N-(4-toluenesulfonyl)-2-(3-phenyl-1-(phenylthio)propyl)pyrrolidine 
• 1613582-57-2 (2S,3R)-N-(4-toluenesulfonyl)-2-phenethyl-3-(phenylthio)piperidine 
• 1613582-53-8 (E)-4-methyl-N-(8-phenyloct-5-en-1-yl)benzenesulfonamide 
• 1613582-51-6 C₁₄H₁₇N 
• 1613582-43-6 (E)-N-(4-toluenesulfonyl)-7-phenylhept-4-enylamine 
• 1613582-66-3 (2S,7R)-N-(4-toluenesulfonyl)-2-(3-phenyl-1-(phenylthio)propyl)piperidine 
• 1346899-36-2 C₁₃H₁₇BrO 
• 1639366-21-4 C₁₃H₁₇BrO 
• 1346899-13-5 C₂₈H₄₁NO₂S 

Relevant articles and documents

Catalytic Hydroetherification of Unactivated Alkenes Enabled by Proton-Coupled Electron Transfer

We report a catalytic, light-driven method for the intramolecular hydroetherification of unactivated alkenols to furnish cyclic ether products. These reactions occur under visible-light irradiation in the presence of an IrIII-based photoredox catalyst, a Br?nsted base catalyst, and a hydrogen-atom transfer (HAT) co-catalyst. Reactive alkoxy radicals are proposed as key intermediates, generated by direct homolytic activation of alcohol O?H bonds through a proton-coupled electron-transfer mechanism. This method exhibits a broad substrate scope and high functional-group tolerance, and it accommodates a diverse range of alkene substitution patterns. Results demonstrating the extension of this catalytic system to carboetherification reactions are also presented.

Chiral Selenide-Catalyzed Enantioselective Construction of Saturated Trifluoromethylthiolated Azaheterocycles

An indane-based, bifunctional, chiral selenide catalyst has been developed. The new catalyst is efficient for the enantioselective synthesis of saturated azaheterocycles possessing a trifluoromethylthio group. The desired products were obtained in good yields with high diastereo- and enantioselectivities.

Remote control of regio- and diastereoselectivity in the hydroformylation of bishomoallylic alcohols with catalytic amounts of a reversibly bound directing group

(Figure Presented) Remote and reversible! Phosphinites serve as reversibly bound directing groups for the remote control of the regio- and diastereoselective hydroformylation of bishomoallylic alcohols (see scheme; r.r: regioisomer ratio). The distance between the double bond and the functional hydroxy group to which the directing group is reversibly bound is the longest ever reported.