22414-62-6Relevant articles and documents
Two new catalysts for the dehydrogenative coupling reaction of carboxylic acids with silanes - Convenient methods for an atom-economical preparation of silyl esters
Liu, Guo-Bin,Zhao, Hong-Yun,Thiemann, Thies
, p. 2717 - 2727 (2008/02/12)
Tris(triphenylphosphine)cuprous chloride [Cu(PPh3)3Cl] has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol% Cu(PPh3)3Cl, dehydrosilylation reactions in acetonitrile afforded the corresponding silyl esters at 80°C in good yields. It was noted that triphenylphosphine itself also functions as an adequate catalyst for the reaction. Copyright Taylor & Francis Group, LLC.
Convenient synthesis of tributylsilyl methacrylate
Mancardi, David,Sindt, Michele,Paul, Jean-Michel,Mieloszynski, Jean-Luc
, p. 3873 - 3878 (2008/02/10)
To replace antifouling paints containing organotin compounds and to develop self-polishing coatings free of toxicity, we describe here the synthesis of a new polymerizable molecule containing silicon: tributylsilyl methacrylate. Copyright Taylor & Francis Group, LLC.
Process for the production of silyl carboxylate monomers
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Page 6; 7; 8, (2008/06/13)
A process for the production of hydrocarbyl silyl unsaturated carboxylates of formula (I) is described, wherein n represents a number of dihydrocarbylsiloxane units from 0 to 1000. The process includes the reaction of an unsaturated carboxylic acid of formula (II) with a hydrocarbyl silyl compound of formula (III) the said reaction being carried out in the presence of a silaphilic catalyst.