230-46-6 Usage
Description
1,7-Phenanthroline, an aza-analog of phenanthrene, is a chemical compound known for its inhibitory effect on the germination and growth of plants. It has been found to be mutagenic in the Ames test using Salmonella typhimurium TA100 in the presence of a rat liver S9 fraction. Supramolecular assemblies of 1,2,4,5-benzenetetracarboxylic acid with 1,7-phenanthroline (aza donor molecule) have been investigated for their potential applications.
Uses
Used in Chemical Synthesis:
1,7-Phenanthroline is used as a chemical intermediate for the production of [1,7]phenanthroline-8-carbonitrile with hydrocyanic acid and potassium salt at a specific temperature. This synthesis is crucial for creating compounds with various applications in different industries.
Used in Plant Growth Inhibition:
1,7-Phenanthroline is used as a growth inhibitor in the agricultural industry to control the germination and growth of plants. Its inhibitory properties can be beneficial in managing plant growth and development, as well as in controlling weed populations.
Used in Chemical Research:
1,7-Phenanthroline serves as an important compound in chemical research, particularly in the study of supramolecular assemblies. Its interaction with other molecules, such as 1,2,4,5-benzenetetracarboxylic acid, has been investigated to understand its potential applications in various fields.
Check Digit Verification of cas no
The CAS Registry Mumber 230-46-6 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 2,3 and 0 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 230-46:
(5*2)+(4*3)+(3*0)+(2*4)+(1*6)=36
36 % 10 = 6
So 230-46-6 is a valid CAS Registry Number.
InChI:InChI=1/C12H8N2/c1-3-9-5-6-11-10(4-2-7-13-11)12(9)14-8-1/h1-8H
230-46-6Relevant articles and documents
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Perkampus,Rother
, p. 597 (1974)
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Heteroannulation of 3-Bis(methylthio)acrolein with Aromatic Amines - A Convenient Highly Regioselective Synthesis of 2-(Methylthio)quinolines and their Benzo/Hetero Fused Analogs: A Modified Skraup Quinoline Synthesis
Panda, Kausik,Siddiqui, Iffat,Mahata, Pranab K.,Ila, Hiriyakkanavar,Junjappa, Hiriyakkanavar
, p. 449 - 452 (2007/10/03)
A simple and efficient synthesis of 2-(methylthio)quinolines and their condensed analogs has been developed through acid-induced cyclocondensation of their respective anilines or aromatic diamines with 3-bis(methylthio)acrolein. The 2-(methylthio) functionality in these quinolines could be either dethiomethylated or replaced by various nitrogen and carbon nucleophiles to afford 2-substituted quinolines.
Some Reactions of N-Alkoxycarbonyl Reissert Compounds with Heterocumulenes: Formation of the Imidazoisoquinoline and Imidazophthalazine Systems and Related Chemistry
Uff, Barrie C.,Budhram, Ronald S.,Ghaem-Maghami, Ghobad,Mallard, Angela S.,Harutunian, Vahak,et al.
, p. 1901 - 1930 (2007/10/02)
Chloroformate derived Reissert compounds of isoquinoline and of phenanthridine on treatment with base undergo cyclisation with isothiocyanates to give in good yields corresponding imidazoisoquinoline and imidazophenanthroline derivatives.Phthalazine Reissert compound analogues give open chain adducts under the same conditions which can be cyclised to derivatives of the novel imidazophthalazine system by heating in the presence of molecular sieves.When carbon disulphide is the heterocumulene cyclisation is not observed but open chain dithio-ester derivatives can be isolated on alkylation of the intermediate sodium salts.