23367-36-4

Basic information

• Product Name: Benzene, 1,1'-(1-chloro-1,2-ethenediyl)bis[4-methoxy-, (Z)-
• CAS NO: 23367-36-4
• Molecular Formula: C16H15ClO2
• Molecular Weight: 274.747
• Mol File: 23367-36-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-chloro-1,2-ethenediyl)bis[4-methoxy-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-chloro-1,2-ethenediyl)bis[4-methoxy-, (Z)-(23367-36-4)
• EPA Substance Registry System: Benzene, 1,1'-(1-chloro-1,2-ethenediyl)bis[4-methoxy-, (Z)-(23367-36-4)

Safety Data

• Hazardous Substances Data: 23367-36-4(Hazardous Substances Data)

Upstream product

• 79-37-8 oxalyl dichloride 
• 120-44-5 1,4-di(4-methoxyphenyl)ethanone 
• 2132-62-9 4,4'-dimethoxydiphenylacetylene 
• 4693-91-8 4-methoxyphenyl-acetic chloride 

Downstream Products

• 51048-43-2 1,1,2,2-tetrakis(4-methoxyphenyl)ethane 
• 116028-51-4 1,1,1,2-tetrakis-(4-methoxy-phenyl)-ethane 
• 2132-62-9 4,4'-dimethoxydiphenylacetylene 
• 135582-74-0 1,2,3,4-tetra-p-anisyl-5-methylfulvene 

Relevant articles and documents

Iridium-Catalyzed Hydrochlorination and Hydrobromination of Alkynes by Shuttle Catalysis

Described herein are two different methods for the synthesis of vinyl halides by a shuttle catalysis based iridium-catalyzed transfer hydrohalogenation of unactivated alkynes. The use of 4-chlorobutan-2-one or tert-butyl halide as donors of hydrogen halides allows this transformation in the absence of corrosive reagents, such as hydrogen halides or acid chlorides, thus largely improving the functional-group tolerance and safety profile of these reactions compared to the state-of-the-art. This method has granted access to alkenyl halide compounds containing acid-sensitive groups, such as tertiary alcohols, silyl ethers, and acetals. The synthetic value of those methodologies has been demonstrated by gram-scale synthesis where low catalyst loading was achieved.