2339-39-1Relevant articles and documents
Synthesis of vinylgermanes via the Au/TiO2-catalyzed cis-1,2-digermylation of alkynes and the regioselective hydrogermylation of allenes
Louka, Anastasia,Stratakis, Manolis
, p. 3599 - 3603 (2021/05/04)
In the presence of Au/TiO2 (1 mol %), terminal alkynes react quantitatively with stoichiometric amounts of the unactivated digermane Me3Ge-GeMe3, forming exclusively cis-1,2-digermylated alkenes. We also establish the Au/TiO2-catalyzed hydrogermylation of terminal allenes with Et3GeH, which exhibits a highly regioselective mode of addition on the more substituted double bond forming vinylgermanes. Additionally, we provide preliminary results regarding the Pd nanoparticle-catalyzed C-C coupling of 1,2-digermyl alkenes with aryl iodides.