241-34-9Relevant articles and documents
Benzo[1,2-b:4,5-b′]bis[b]benzothiophene as solution processible organic semiconductor for field-effect transistors
Gao, Peng,Beckmann, Dirk,Tsao, Hoi Nok,Feng, Xinliang,Enkelmann, Volker,Pisula, Wojciech,Muellen, Klaus
, p. 1548 - 1550 (2008)
Coplanar benzo[1,2-b:4,5-b′]bis[b]benzothiophenes (1a, 1b) for the application in organic field-effect transistors were synthesized by a simple two-step procedure involving triflic acid induced ring-closure reaction; such solution processed devices show a hole mobility of up to 0.01 cm2 V-1 s-1. The Royal Society of Chemistry.
Compound containing fused heterocycle structure, application of compound and organic electroluminescent device
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Paragraph 0134-0135; 0137, (2021/05/05)
The invention relates to the field of organic electroluminescent devices, and discloses a compound containing a fused heterocycle structure, an application of the compound and an organic electroluminescent device. The compound has the general formula structure shown in the formula (I); the compound has a high glass transition temperature, a high decomposition temperature and a high refractive index; and when the compound is applied to a covering layer on a device, the light extraction efficiency of the cathode can be improved, so that the luminous efficiency of the device is improved, and the service life of the device is prolonged.
Copper-Catalyzed Double S-Arylation of Potassium Thioacetate with Dibenziodolium Triflates: Facile Synthesis of Unsymmetrical Dibenzothiophenes
Shimizu, Masaki,Ogawa, Mai,Tamagawa, Tomokazu,Shigitani, Ryosuke,Nakatani, Masaki,Nakano, Yoshiki
supporting information, p. 2785 - 2788 (2016/07/07)
Much interest has been paid to cyclic diaryliodonium salts as bis(electrophile)s in transition-metal-catalyzed annulation reactions to produce polycyclic (hetero)aromatic hydrocarbons. Herein, we report that dibenziodolium triflates smoothly react with potassium thioacetate in the presence of CuCl2in THF or DMSO at 100–110 °C to afford the corresponding dibenzothiophenes in good-to-high yields. The coupling reaction tolerates reactive functional groups such as chloro and cyano and serves as a facile and reliable method for the synthesis of unsymmetrical dibenzothiophenes.
Synthesis of dibenzothiophenes by pd-catalyzed dual C-H activation from diaryl sulfides
Che, Rui,Wu, Zhiqing,Li, Zhengkai,Xiang, Haifeng,Zhou, Xiangge
supporting information, p. 7258 - 7261 (2014/06/23)
Palladium-catalyzed dual C-H functionalization of diaryl sulfides to form dibenzothiophenes (DBTs) by oxidative dehydrogenative cyclization is reported. This protocol afforded various DBTs in moderate to good yields with tolerance of a wide variety of substrates. Benzo[1,2-b:4,5-b]bis[b]benzothiophene was successfully synthesized by this method, which was used as an organic semiconductor for field-effect transistors.