2419-67-2

Basic information

• Product Name: 1-(4-Methoxyphenyl)-4,4-dimethyl-1-penten-3-one
• Synonyms: 1-(4-Methoxyphenyl)-4,4-dimethyl-1-penten-3-one
• CAS NO: 2419-67-2
• Molecular Formula: C₁₄H₁₈O₂
• Molecular Weight: 218.2915
• Mol File: 2419-67-2.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 348.3°Cat760mmHg
• Flash Point: 149.7°C
• Appearance: /
• Density: 1.003g/cm³
• Vapor Pressure: 5.09E-05mmHg at 25°C
• Refractive Index: 1.531
• CAS DataBase Reference: 1-(4-Methoxyphenyl)-4,4-dimethyl-1-penten-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-Methoxyphenyl)-4,4-dimethyl-1-penten-3-one(2419-67-2)
• EPA Substance Registry System: 1-(4-Methoxyphenyl)-4,4-dimethyl-1-penten-3-one(2419-67-2)

Safety Data

• Hazardous Substances Data: 2419-67-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H18O2/c1-14(2,3)13(15)10-7-11-5-8-12(16-4)9-6-11/h5-10H,1-4H3/b10-7+

Upstream product

• 75-97-8 3,3-dimethyl-butan-2-one 
• 123-11-5 4-methoxy-benzaldehyde 
• 17510-46-2 3,3-dimethyl-2-(trimethylsilyl)oxy-1-butene 
• 3900-79-6 toluene-4-sulfonic acid isopropylidenehydrazide 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 

Downstream Products

• 97792-22-8 5-(4-Methoxy-phenyl)-2,2,8,8-tetramethyl-nonane-3,7-dione 
• 58344-43-7 (E)-1-(4-Methoxy-phenyl)-4,4-dimethyl-pent-1-en-3-ol 
• 1283088-27-6 C₁₇H₂₀O 
• 1465270-48-7 C₂₄H₂₆O₃S 
• 7475-25-4 (1RS,2SR)-1,2-dibromo-1-(4-methoxy-phenyl)-4,4-dimethyl-pentan-3-one 
• 84669-23-8 (E)-1-(4-Methoxy-phenyl)-4,4-dimethyl-pent-1-en-3-one O-methyl-oxime 
• 84669-28-3 (E)-1-(4-Methoxy-phenyl)-4,4-dimethyl-pent-1-en-3-one O-benzyl-oxime 
• 84669-19-2 1-Aminooxy-1-(4-methoxy-phenyl)-4,4-dimethyl-pentan-3-one oxime 
• 201804-19-5 1-((2R,3S)-4-methoxyphenyloxiranyl)-2,2-dimethylpropan-1-one 
• 75472-91-2 (2S,3S)-5-(2-dimethylaminoethyl)-3-hydroxy-2-(4-methoxyphenyl)-2,3-dihydro-1,5-benzothiazepin-4(5H)-one hydrochloride 

Relevant articles and documents

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A visible-light-driven and room temperature photo-Wolff-Kischner reaction of sulfur ylides and N-tosylhydrazones has been developed for the first time to provide modular access to alkene synthesis. The high functional group tolerance and broad substrate scope were demonstrated by more than 60 examples. Both E- and Z-olefinic stereochemistry in the products could be controlled with excellent stereoselectivity. A series of mechanistic studies support that the reaction should proceed through a radical-carbanion crossover pathway, specifically involving addition of photo-generated sulfur ylide radical cations to N-tosylhydrazones to form carbanions and subsequent Wolff-Kischner process.

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