242461-31-0Relevant articles and documents
Lewis acid trapping of an elusive copper-tosylnitrene intermediate using scandium triflate
Kundu, Subrata,Miceli, Enrico,Pfaff, Florian Felix,Braun, Beatrice,Greco, Claudio,Ray, Kallol,Farquhar, Erik,Kuhlmann, Uwe,Hildebrandt, Peter
supporting information, p. 14710 - 14713,4 (2020/08/24)
High-valent copper-nitrene intermediates have long been proposed to play a role in copper-catalyzed aziridination and amination reactions. However, such intermediates have eluded detection for decades, preventing the unambiguous assignments of mechanisms.