24325-70-0

Basic information

• Product Name: TRANS4METHYL4NITROSTILBENE
• Synonyms: (E)-1-Methyl-4-(2-(4-nitrophenyl)ethenyl)benzene;(E)-4-Methyl-4'-nitrostilbene;Benzene, 1-methyl-4-(2-(4-nitrophenyl)ethenyl)-, (E)-;Ccris 8544
• CAS NO: 24325-70-0
• Molecular Formula: C₁₅H₁₃NO₂
• Molecular Weight: 239.26922
• Mol File: 24325-70-0.mol
• Article Data: 20

Chemical Properties

• Boiling Point: 359.5°C at 760 mmHg
• Flash Point: 159.5°C
• Appearance: /
• Density: 1.191g/cm³
• Vapor Pressure: 4.9E-05mmHg at 25°C
• Refractive Index: 1.67
• CAS DataBase Reference: TRANS4METHYL4NITROSTILBENE(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS4METHYL4NITROSTILBENE(24325-70-0)
• EPA Substance Registry System: TRANS4METHYL4NITROSTILBENE(24325-70-0)

Safety Data

• Hazardous Substances Data: 24325-70-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H13NO2/c1-12-2-4-13(5-3-12)6-7-14-8-10-15(11-9-14)16(17)18/h2-11H,1H3/b7-6+

Upstream product

• 104-03-0 4-nitrobenzeneacetic acid 
• 104-87-0 4-methyl-benzaldehyde 
• 51042-50-3 4-nitrobenzyltriphenylarsonium bromide 
• 2609-49-6 diethyl p-nitrobenzylphosphonate 
• 17556-09-1 cis-4-Methyl-4'-nitro-stilben 
• 2767-70-6 (p-nitrobenzyl)triphenylphosphonium bromide 
• 456-27-9 4-nitrobenzenediazonium tetrafluoroborate 
• 73839-45-9 (E)-trimethyl[2-(4-methylphenyl)ethenyl]silane 
• 72316-17-7 (E)-2-(4-methylphenyl)ethenylboronic acid 
• 586-78-7 para-nitrophenyl bromide 
• 603-32-7 triphenyl-arsane 
• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 622-97-9 1-ethenyl-4-methylbenzene 
• 100-00-5 4-chlorobenzonitrile 

Downstream Products

• 14366-78-0 E-1-(4-bromomethylphenyl)-2-(4-nitrophenyl)ethene 
• 7314-08-1 trans-p-amino-p'-methylstilbene 
• 15794-96-4 (4-Nitro-phenyl)-(4-tolyl)-1,2-dibrom-aethan 
• 885101-88-2 E-triphenyl-[4-(2-(4-nitrophenyl)ethenyl)benzyl]phosphonium bromide 
• 1290638-10-6 E,E-1-[2-(4-nitrophenyl)ethenyl]-4-[2-(3,4,5-trimethoxyphenyl)ethenyl]benzene 
• 1290638-01-5 E,E-1-[2-(4-nitrophenyl)ethenyl]-4-[2-(3,5-dimethoxyphenyl)ethenyl]benzene 
• 1290638-02-6 E,E-1-[2-(4-nitrophenyl)ethenyl]-4-[2-(2,6-dimethoxyphenyl)ethenyl]benzene 

Relevant articles and documents

N-Heterocyclic carbene palladium (II)-pyridine (NHC-Pd (II)-Py) complex catalyzed heck reactions

A mild, efficient, and practical catalytic system for the synthesis of highly privileged stilbene pharmacophores is reported. This system uses N-heterocyclic carbene palladium (II) Pyridine (NHC-Pd (II)-Py) complex to catalyze the formation of carbon-carbon bonds between olefin derivatives and various bromide. This simple, gentle and user-friendly method can offer a variety of stilbene products in excellent yields under solvent-free condition. And its scale-up reaction has excellent yield and this system can be applied to industrial fields. The utility of this method is highlighted by its universality and modular synthesis of a series of bioactive molecules or important medical intermediates.

Transition-Metal-Free Catalytic Carboalkoxylation of Styrenes at Room Temperature

Herein, we describe the first transition-metal-free catalytic carboalkoxylation of styrenes with aryl diazonium salts by Meerwein addition in the presence of a phenalenyl ligand at room temperature without requiring any light stimulation. This three-compo

Pd(OAc)2 immobilized on imine-functionalized microporous covalent triazine polymer as efficient heterogeneous catalyst for Mizoroki–Heck cross-coupling reaction

A template consisting of Pd(OAc)2 immobilized on imine-functionalized microporous covalent triazine polymer network (Pd/TATAE) was synthesized and found to be an efficient and recyclable heterogeneous solid catalyst for Mizoroki–Heck C–C coupling of styrene with substituted aryl halides under mild reaction conditions and without addition of any ligand or additives. Furthermore, Pd/TATAE could be recycled for nine consecutive cycles with minor loss of catalytic activity. Finally, the Pd/TATAE catalyst showed good catalytic activity with excellent yield of 96?% and high turnover number of 3349.