245-57-8Relevant articles and documents
Cyclocondensation of n-(prop-2-yn-1-yl)- and n-(penta-2,4-diyn-1-yl)- o-phenylenediamines with phenyl isothiocyanate and carbon disulfide
Novikov,Danilkina,Balova
scheme or table, p. 758 - 766 (2012/01/16)
The cyclocondensation of N-(prop-2-yn-1-yl)-o-phenylenediamines with phenyl isothiocyanate leads to the formation of 1-(prop-2-yn-1-yl)-1,3-dihydro-2H- benzimidazole-2-thiones irrespective of the substituent nature at the triple bond. Reactions of both mo
Heterocyclization of 2-Allylthiobenzimidazoles into Derivatives of Benzimidazo-1,3-Thiazines
Korotkikh, N. I.,Raenko, G. F.,Shvaika, O. P.
, p. 359 - 363 (2007/10/03)
It was found that bromination of 2-allylthiobenzimidazoles in organic solvents forms products of addition of bromine to the olefin bond - 2,3-dibromopropylthiobenzimidazoles, whch spontaneously or on heating cyclize into 3-bromobenzimidazo-1,3-thiazines or cyclodehydrobromination products - 2H- or 4H-benzimidazo-1,3-thiazines.