25022-93-9Relevant articles and documents
Hypovalent Radicals. Chemical Trapping of Electrogenerated Diazoalkane Anion Radicals
Triebe, F. M.,Hawley, M. Dale,McDonald, Richard N.
, p. 574 - 575 (2007/10/02)
Diazoalkane anion radicals produced by electroreduction of diazodiphenylmethane (Ph2CN2) and 9-diazofluorene (FlN2) in the presence of certain proton donors yield the corresponding hydrazones (R2C=NNH2); formation of diphenylmethane from electroreduction of Ph2CN2 is shown to proceed by formation of the carbene anion radical Ph2C*-.
Radical Anions in the Reduction of Benzophenone Azine
Handoo, Kishan L.,Handoo, Sudesh K.
, p. 684 - 687 (2007/10/02)
Cyclic voltammetric reduction of benzophenone azine produces radical anions and dianions in two reversible one-electron steps in dimethylformamide.A similar sequence of reaction occurs when the azine is reduced with sodium naphthalenide in degassed tetrahydrofuran.ESR-spectrum is reported for the radical anion and the scope of the reaction leading to the products of electron-transfer reduction with sodium naphthalenide has been investigated.