25227-79-6Relevant articles and documents
Tangentially coupled π systems and their through-space interaction - Trichromophoric perylene dyes
Langhals, Heinz,Gold, Josef
, p. 654 - 659 (1996)
Three perylene tetracarboxylic bisimide chromophores have been attached to a benzene ring in m-position (3). In this way steric and through-bond interactions of the chromophores are minimized and their through-space-interactions can be studied for which a
NON-COORDINATING ANION TYPE ACTIVATORS FOR USE WITH POLYOLEFIN POLYMERIZATION CATALYSTS
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Paragraph 0254, (2021/02/12)
The present disclosure is related to activator compounds represented by: [Ar(E11R11R22H)xx(E22R33R44)yy][QR55R66R77R88]zz In the formula Ar is a C66-C3030 aromatic hydrocarbyl group, provided that if Ar is a multicyclic ring, then each E11 and each E22 are substitutions on a single ring. Also, x is 1 to 4; y is 0 to 3; z = x; and x+y is 2 to 6. Each of E11 and E22 are independently selected from nitrogen or phosphorous and Q is selected from group 13 of the Periodic Table of the Elements. Additionally, each of R11, R22, R33 and R44 are independently selected from C11-C4040 aliphatic hydrocarbyl, substituted C11-C4040 aliphatic hydrocarbyl and each of R55, R66, R77, and R88 is independently a C66-C2424 hydrocarbyl or a C66-C2424 substituted hydrocarbyl. The present disclosure also relates to catalyst systems including a catalyst and the activator compound. Also, the present disclosure relates to methods of polymerizing olefins.
Co3O4 nanoparticles prepared by oxidative precipitation method: an efficient and reusable heterogeneous catalyst for N-formylation of amines
Marjani, Ahmad Poursattar,Hosseini, Seyed Ali,Shokri, Zahra,Maleki, Nasim
, p. 413 - 422 (2017/01/14)
Abstract: N-formylation of different amines was carried out with formic acid in the presence of the Co3O4 nanoparticles as an efficient, stable heterogeneous catalyst to give the corresponding formamides under solvent-free conditions. This method has advantages over the reported methods such as high yields, mild conditions, easy work-up and short reaction times. The catalyst was characterized by different techniques such as XRD, SEM and FT-IR spectroscopy. Graphical Abstract: [Figure not available: see fulltext.]