2523-42-4Relevant articles and documents
Polyphenol derivatives of porphyrins containing fluorene units: Synthesis and positive-tone photoresists for 22-nanometer lithography
Vainer, A. Ya.,Dyumaev,Kovalenko,Babuskin, Ya. L.,Krichevskaya,Lubenskii
, p. 174 - 178 (2016)
A new strategy was proposed for the synthesis of polyphenol derivatives of fluorene-containing porphyrins to be used as the base for positive-tone photoresists for lithography with exposure at 13.5 nm wavelength, which allow fabrication of microchips with a size of down to 22 nm. Polyphenols based on fluorenecontaining porphyrins were synthesized for the first time. It was shown that these polyphenol derivatives can be used to obtain positive-tone photoresists with a resolution of 22 nm.
An investigation of the effect of conjugation on fluorene based chromophores; Optoelectronic and electrochemical behavior
Mahar, Jamaluddin,Saeed, Aamer,Belfield, Kevin D.,Iqbal, Anila,Irfan, Madiha,Shabir, Ghulam,Larik, Fayaz Ali,Channar, Pervaiz Ali
, p. 385 - 392 (2017)
The requisition of small light emitting organic molecules is on the rise in the field of organic electronics. This study is aimed at synthesis of fluorene based chromophores which possess promising optoelectronic properties. The characterization of synthesized derivatives was carried out by spectroscopy (1H-NMR and 13C-NMR) and spectrometry (EI-MS). The optical properties evaluated by using UV-Vis spectroscopy, were from 394 to 420 nm, Fluorescence ranged 48 nm-113 nm, HOMO energy levels are ?6.75 eV to ?7.15 eV LUMO -4.08 to ?4.52eV with a band gap energy values 2.63–2.67 eV. The band gap energy values suggest that these synthesized molecules can be manipulated in the designing of blue and green OLEDS.
Solid-state construction of zigzag periphery: Via intramolecular C-H insertion induced by alumina-mediated C-F activation
Akhmetov, Vladimir,Amsharov, Konstantin,F?rtsch, Andreas,Feofanov, Mikhail
supporting information, p. 12325 - 12328 (2021/11/30)
Caryl-F bond activation has become an important and quickly developing method for construction of carbon-based materials. We report that alumina-mediated C-F bond activation (AmCFA) enables construction of PAHs with zigzag periphery. This method includes
Preparation method of photoelectric material intermediate (by machine translation)
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Paragraph 0008; 0012; 0013, (2019/10/08)
The invention discloses a preparation method of a photoelectric material intermediate, and is not reported in China at present. To the preparation method provided by the invention, the raw 2 material fluorene -9 is used as a series of operations such as single iodination and the C-N acenyman coupling, crude purification 9 and 9 - the like 4 -2 - 99.0%. The preparation method provided by the invention is simple to operate and suitable for industrial production. (by machine translation)