25926-16-3Relevant articles and documents
Synthesis and kinetic study of a series of chloro- and m-carboxypyridium triazinyl reactive dyes
Huang, Huei-Chin,Wu, Chun-Guey
, (2021)
Five monochloro-s-triazinyl reactive dyes (MCT) and five m-carboxypyridium-s-triazinyl reactive dyes (NTR) were synthesised with the same red chromophore bearing an –NHCN, –OCH3, –CH3NSO2CH3, –N-methyl phenyl or –OH group as ‘second-leg’ substituents. A kinetic study of the hydrolysis of these dyes was conducted, and the rate constant (kobs) and half-life time values were determined. The kobs of the MCT and NTR dyes was found to follow the order –OCH3 > –CH3NSO2CH3 > –N-methyl phenyl > –NHCN > –OH, which was approximately in agreement with the values obtained for the Hammett substituent constants. Overall, the higher the electron-donating property of the substituent on meta-position to the leaving group in the triazine ring, the lower the hydrolysis rate constant.
Fiber reactive dyestuffs
-
Page/Page column 20, (2010/11/24)
A fiber reactive dyestuff of the following formula (I) wherein the definition of D, R, R1, R2, X and Z have the same meaning as given in the specification. The fiber reactive dyestuff of the present invention is suitable for dyeing and printing on cellulose fiber or fiber materials containing cellulose. Dyed material with various excellent properties in dyed color can be obtained, showing especially outstanding performance in the property of wash fastness, build-up and chlorine fastness.
Bridged disazo compounds
-
Example 146, (2008/06/13)
Compounds of formula (I) with the meanings of D, R1, R2, X and Y as given in claim 1 can be used as paper dyes or direct dyes or for the preparation of ink-jet inks.