26237-85-4

Basic information

• Product Name: 4,5α-epoxy-3,6-dimethoxy-N-methyl-2'-phenyl-6α,14α-endo-ethenopyrrolo<3,4-i>isomorphinane-1',3'-dione
• CAS NO: 26237-85-4
• Molecular Weight: 484.552
• Mol File: 26237-85-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4,5α-epoxy-3,6-dimethoxy-N-methyl-2'-phenyl-6α,14α-endo-ethenopyrrolo<3,4-i>isomorphinane-1',3'-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 4,5α-epoxy-3,6-dimethoxy-N-methyl-2'-phenyl-6α,14α-endo-ethenopyrrolo<3,4-i>isomorphinane-1',3'-dione(26237-85-4)
• EPA Substance Registry System: 4,5α-epoxy-3,6-dimethoxy-N-methyl-2'-phenyl-6α,14α-endo-ethenopyrrolo<3,4-i>isomorphinane-1',3'-dione(26237-85-4)

Safety Data

• Hazardous Substances Data: 26237-85-4(Hazardous Substances Data)

Upstream product

• 941-69-5 N-phenyl-maleimide 
• 115-37-7 thebaine 

Downstream Products

• 26237-86-5 4,5α-epoxy-3,6-dimethoxy-17-methyl-1'-phenyl-(7β,8β)-8,1',2',5'-tetrahydro-7H-6α,14α-etheno-pyrrolo[3',4':7,8]morphinane 
• 1416673-25-0 1-[(3-morpholin-4-yl)propynyl]-7α,8α-(2,5-dioxo-N-phenylpyrrolidino)[3,4-h]-6,14-endo-etheno-6,7,8,14-tetrahydrothebaine 
• 1039433-37-8 1-ethynyl-7α,8α-(2,5-dioxo-N-phenylpyrrolidino)[3,4-h]-6,14-endo-etheno-6,7,8,14-tetrahydrothebaine 
• 1039433-31-2 1-(2-trimethylsilylethynyl)-7α,8α-(2,5-dioxo-N-phenylpyrrolidino)[3,4-h]-6,14-endo-etheno-6,7,8,14-tetrahydrothebaine 
• 1008355-59-6 1-bromo-4,5α-epoxy-6α,14-etheno-3,6-dimethoxy-17-methyl-1'-phenyl-2',5',7β,8β-tetrahydro-1'H-14α-pyrrolo[3',4':7,8]morphinan-2',5'-dione 

Relevant articles and documents

New Studies and a Reinvestigation on Cycloadditions of (-)-Thebaine: Asymmetrical Diels-Alder Reactions with a Conformationally Fixed Chiral Diene

Some novel Diels-Alder reactions of the opium alkaloid (-)-thebaine (1) as an electron-rich diene and a reinvestigation of its reactions with cyclic and acyclic dienophiles are described.The ?-facial selectivity has been studied on the basis of structural analyses of the cycloadducts.Some related results on cycloaddition reactions of 1-methoxy-1,3-cyclohexadiene (11) are also reported. - Key Words: (-)-Thebaine / 1,3-Cyclohexadiene, 1-methoxy / Diels-Alder Reactions / Alkaloids