26429-97-0Relevant articles and documents
Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes
Huang, Jiaxin,Li, Jie,Yang, Wen,Zhang, Kezhuo,Zhao, Pei,Zhao, Wanxiang
supporting information, p. 302 - 305 (2022/01/03)
The Co-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes were realized by a ligand-controlled strategy. The remote hydroboration with dcype provided borylethers, while xantphos favored the formation of silyl enol ethers.
Trifluoromethylation of Unactivated Alkenes with Me3SiCF3 and N-Iodosuccinimide
Yang, Xinkan,Tsui, Gavin Chit
supporting information, p. 1521 - 1525 (2019/03/07)
A novel approach to the trifluoromethylation of unactivated alkenes is presented. This reaction is promoted by N-iodosuccinimide (NIS) under visible light irradiation without the need for photocatalysts. The mild conditions allow the direct synthesis of u
Formation of Enol Ethers by Radical Decarboxylation of α-Alkoxy β-Phenylthio Acids
Palanivel, Ashokkumar,Mubeen, Sidra,Warner, Thomas,Ahmed, Nayeem,Clive, Derrick L. J.
, p. 12542 - 12552 (2019/10/19)
Enol ethers are formed by radical decarboxylation of α-alkoxy β-phenylthio acids via the corresponding Barton esters. The phenylthio acids were usually made by the known regioselective reaction of α,β-epoxy acids with PhSH in the presence of InCl3, followed by O-alkylation of the resulting alcohol. In one case, thiol addition to an α,β-unsaturated ethoxymethyl ester was used.