2648079-79-0

Basic information

• Product Name: S-(trifluoromethyl)thianthrenium triflate
• CAS NO: 2648079-79-0
• Molecular Weight: 434.404
• Mol File: 2648079-79-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: S-(trifluoromethyl)thianthrenium triflate(CAS DataBase Reference)
• NIST Chemistry Reference: S-(trifluoromethyl)thianthrenium triflate(2648079-79-0)
• EPA Substance Registry System: S-(trifluoromethyl)thianthrenium triflate(2648079-79-0)

Safety Data

• Hazardous Substances Data: 2648079-79-0(Hazardous Substances Data)

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 92-85-3 Thianthrene 

Downstream Products

• 25199-76-2 3-(trifluoromethyl)quinoline 
• 718-64-9 1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol 
• 17556-41-1 2,2,2-trifluoro-1-(4-fluorophenyl)ethanol 
• 1086836-85-2 methyl 4-(2,2,2-trifluoro-1-hydroxyethyl)benzoate 
• 456-56-4 phenyl trifluoromethylsulfide 
• 1579-80-2 (3,3,3-trifluoropropyl)benzene 
• 401-75-2 trifluoromethylcyclohexane 
• 1422056-42-5 N-(5,5,5-trifluoropentyl)benzamide 

Relevant articles and documents

Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF3+, CF3?, and CF3-Reactivity

Here we report the synthesis and application of trifluoromethyl thianthrenium triflate (TT-CF3+OTf-) as a novel trifluoromethylating reagent, which is conveniently accessible in a single step from thianthrene and triflic anhydride. We demonstrate the use of TT-CF3+OTf- in electrophilic, radical, and nucleophilic trifluoromethylation reactions.