2715-05-1

Basic information

• Product Name: Benzene, 1-(phenylsulfonyl)-3-(trifluoromethyl)-
• CAS NO: 2715-05-1
• Molecular Formula: C13H9F3O2S
• Molecular Weight: 286.274
• Mol File: 2715-05-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(phenylsulfonyl)-3-(trifluoromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(phenylsulfonyl)-3-(trifluoromethyl)-(2715-05-1)
• EPA Substance Registry System: Benzene, 1-(phenylsulfonyl)-3-(trifluoromethyl)-(2715-05-1)

Safety Data

• Hazardous Substances Data: 2715-05-1(Hazardous Substances Data)

Upstream product

• 401-78-5 3-bromo-1-trifluoromethylbenzene 
• 873-55-2 sodium benzenesulfonate 
• 401-81-0 m-trifluoromethylphenyl iodide 
• 66003-76-7 Diphenyliodonium triflate 
• 591-51-5 phenyllithium 
• 71-43-2 benzene 
• 16883-74-2 lithium benzenesulfinate 
• 1121974-62-6 C₇H₄F₃O₂S^(1-)*Li⁽¹⁺⁾ 
• 1330786-68-9 (3-trifluoromethylphenyl)(4-methoxyphenyl)iodonium p-toluenesulfonate 
• 108-98-5 thiophenol 
• 2559-68-4 (3-nitro-5-trifluoromethyl-phenyl)-phenyl sulfone 
• 401-94-5 3-nitro-5-(trifluoromethyl)-phenylamine 
• 114650-56-5 C₁₃H₉F₃N₂S 
• 2715-07-3 (3-trifluoromethyl-phenyl)-phenyl sulfide 

Relevant articles and documents

Nickel-Catalyzed Synthesis of Diaryl Sulfones from Aryl Halides and Sodium Sulfinates

A novel nickel-catalyzed cross-coupling of sulfinic acid salts with aryl halides is described. The reaction provides access to various diaryl sulfones in moderate to excellent yields. A broad range of functional groups and heteroaromatic compounds is tolerated under the reaction conditions.

One-pot synthesis of aryl sulfones from organometallic reagents and iodonium salts

A transition-metal-free arylation of lithium, magnesium, and zinc sulfinates with diaryliodonium salts is described. The sulfinic acid salts were prepared from the reaction of the corresponding organometallic reagents and sulfur dioxide. Combination of the three single steps (preparation of the organometallic compound, sulfinate formation, and arylation) leads to a one-pot sequence for the synthesis of aryl sulfones from simple starting materials. The chemoselectivity of unsymmetrical diaryliodonium salts has been investigated. Potential and limitations of this method will be discussed.

Metal-free synthesis of diaryl sulfones from arylsulfinic acid salts and diaryliodonium salts

An efficient, high-yielding, and transition-metal-free synthesis of diaryl sulfones from arylsulfinic acid salts and diaryliodonium salts has been developed. The mild reaction conditions tolerate a range of functional groups, and unsymmetrical diaryliodonium salts show high chemoselectivity.