27503-90-8

Basic information

• Product Name: 2-allyl-pent-4-enoic acid anilide
• Synonyms: 2-allyl-pent-4-enoic acid anilide
• CAS NO: 27503-90-8
• Molecular Weight: 215.295
• Mol File: 27503-90-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-allyl-pent-4-enoic acid anilide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-allyl-pent-4-enoic acid anilide(27503-90-8)
• EPA Substance Registry System: 2-allyl-pent-4-enoic acid anilide(27503-90-8)

Safety Data

• Hazardous Substances Data: 27503-90-8(Hazardous Substances Data)

Upstream product

• 861357-69-9 2-allyl-penta-1,4-dien-1-one 
• 62-53-3 aniline 
• 40556-27-2 2-allylpent-4-enoyl chloride 
• 99-67-2 2-allyl-4-pentenoic acid 

Relevant articles and documents

Anti-Markovnikov Hydroazidation of Alkenes by Visible-Light Photoredox Catalysis

The anti-Markovnikov hydroazidation of alkenes has been accomplished under visible-light irradiation by using [Ir(dF(CF3)ppy)2(dtbbpy)]PF6 as the photocatalyst and trimethylsilyl azide as the azidating agent. The reactions were greatly facilitated by water, the beneficial effect of which can be attributed to its participation in the reaction as the hydrogen donor, as indicated by deuterium isotope experiments. The reactions proceed under solvent free conditions in the presence of water. 4-Dimethylaminopyridine also exhibited a beneficial effect on the reactions. The present method enabled hydroazidation of several types of unactivated alkenes with good yields and high regioselectivity.