275816-76-7

Basic information

• Product Name: Hexanoic acid, 3-[[(phenylmethoxy)carbonyl]amino]-, (3S)-
• CAS NO: 275816-76-7
• Molecular Formula: C14H19NO4
• Molecular Weight: 265.309
• Mol File: 275816-76-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Hexanoic acid, 3-[[(phenylmethoxy)carbonyl]amino]-, (3S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hexanoic acid, 3-[[(phenylmethoxy)carbonyl]amino]-, (3S)-(275816-76-7)
• EPA Substance Registry System: Hexanoic acid, 3-[[(phenylmethoxy)carbonyl]amino]-, (3S)-(275816-76-7)

Safety Data

• Hazardous Substances Data: 275816-76-7(Hazardous Substances Data)

Upstream product

• 269400-44-4 Z-L-norvalyl(diazo)methane 
• 909019-29-0 C₂₀H₃₃NO₅Si 
• 3426-71-9 Benzyl N-hydroxycarbamate 
• 6728-26-3 (E)-2-Hexenal 
• 147169-15-1 benzyl N-<1-((p-methylphenyl)sulfonyl)butyl>carbamate 
• 909019-16-5 benzyl (tert‐butyldimethylsilyl)oxycarbamate 
• 21691-44-1 Z-L-norvaline 
• 271600-11-4 {(S)-1-[2-Oxo-2-((1R,2R,4R)-1,7,7-trimethyl-2-trimethylsilanyloxy-bicyclo[2.2.1]hept-2-yl)-ethyl]-butyl}-carbamic acid benzyl ester 

Downstream Products

• 221205-09-0 (+)-(3S)-3-benzyloxycarbonylaminohexanol 
• 922705-32-6 phenylmethyl (4S)-6-oxo-4-propyl-1,3-oxazinane-3-carboxylate 
• 922705-45-1 (3S)-3-(methyl{[(phenylmethyl)oxy]carbonyl}amino)hexanoic acid 
• 458-88-8 coniine 

Relevant articles and documents

Enantioselective organocatalytic amine conjugate addition

The first enantioselective organocatalytic amine conjugate addition has been successfully developed. The application of LUMO-lowering iminium catalysis has enabled the highly chemo- and enantioselective 1,4-addition of a rationally designed N-silyloxycarb

Homologation of α-amino acids to β-amino acids: 9-Fluorenylmethyl chloroformate as a carboxyl group activating agent for the synthesis of Nα-protected aminoacyldiazomethanes

An efficient and stereospecific homologation of urethane-protected α-amino acids to β-amino acids by Arndt-Eistert approach using an equimolar mixture of Fmoc-/Boc-/Z-α-amino acid and 9-fluorenylmethyl chloroformate for the acylation of diazomethane synth

Convenient in situ synthesis of nonracemic N-protected β-amino aldehydes from β-amino acids. Applications in Wittig reactions and heterocycle synthesis

N-Z-γ-amino alcohols derived from nonracemic β-amino acids are smoothly oxidised by manganese dioxide in acetonitrile to afford aldehydes which can be trapped in situ in Wittig reactions with carbonyl-substituted phosphoranes. The application of this methodology to the synthesis of the alkaloids (S)-(+)-N-BOC-coniine, (S)-(-)-coniceine and a pipecoline precursor is described.