2767-54-6Relevant articles and documents
Chernoplekova et al.
, (1975)
Spin chemistry of organometallic compounds: Part 1. Interaction of N-bromohexamethyldisilazane with allyltriethylstannane
Taraban, Marc B.,Kruppa, Alexander I.,Rakhlin, Vladimir I.,Grigor'Ev, Stanislav I.,Volkova, Olga S.,Mirskov, Rudolph G.,Leshina, Tatyana V.
, p. 12 - 16 (2001)
It has been shown, on the basis of the analysis of CIDNP effects, that allene and (Me3Si)2NH - major products of the photoinduced reaction of Et3SnCH2CH=CH2 and (Me3Si)2NBr - result from a radical pair comprised of ·CH2CHBrCH2SnEt3 and ·N(SiMe3)2 free radicals. Allene is formed through the β-cleavage of the short-lived homolytic substitution product Et3SnCH2CBr=CH2.
AN INVESTIGATION OF THE MECHANISM OF THE REACTION OF ALLYLTRIETHYLSTANNANE WITH BROMOTRICHLOROMETHANE BY RADIOFREQUENCY PROBING AND CHEMICALLY INDUCED DYNAMIC NUCLEAR POLARIZATION (CIDNP)
Leshina, T.V.,Sagdeev, R.Z.,Polyakov, N.E.,Taraban, M.B.,Valyaev, V.I.,et al.
, p. 295 - 300 (1983)
The methods of radiofrequency probing (RFP) and chemcally induced dynamic nuclear polarization (CIDNP) have been used to study the mechanism of the reaction of allyltriethylstannane with bromotrichloromethane.The CIDNP effects which have been detected prove the presence of radical stages in this reaction.An assumption has been made about a possible radical pathway for the β-decomposition of elementorganic compounds.
Homolytic addition of polyhaloalkanes to α-vinyloxy-ω-trialkylstannoxyalkanes as a new route to 2-perhaloalkylmethyl-substituted 1,3-dioxacyclanes
Arbuzov, P. V.,Voronkov, M. G.,Mirskov, R. G.,Stankevich, V. K.,Kukharev, B. F.,et al.
, p. 1755 - 1757 (2007/10/03)
Photoinduced reactions of α-vinyloxy-ω-trialkylstannoxyalkanes, CH2=CHO(CH2)nOSnEt3 (n = 2 to 4), with polyhaloalkanes results in 2-perhaloalkylmethyl-substituted 1,3-dioxacyclanes. - Key words: α-vinyloxy-ω-trialkylstannoxyalkanes, polyhaloalkanes, photoinduced reactions; 1,3-dioxacyclanes.
