27846-25-9

Basic information

• Product Name: Benzene, [(2-phenylethyl)sulfonyl]-
• CAS NO: 27846-25-9
• Molecular Formula: C14H14O2S
• Molecular Weight: 246.33
• Mol File: 27846-25-9.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-phenylethyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-phenylethyl)sulfonyl]-(27846-25-9)
• EPA Substance Registry System: Benzene, [(2-phenylethyl)sulfonyl]-(27846-25-9)

Safety Data

• Hazardous Substances Data: 27846-25-9(Hazardous Substances Data)

Upstream product

• 60-12-8 2-phenylethanol 
• 873-55-2 sodium benzenesulfonate 
• 536-74-3 phenylacetylene 
• 100-42-5 styrene 
• 108-98-5 thiophenol 
• 3112-85-4 methylphenylsulfonate 
• 144397-85-3 Carbonic acid 1-methylethyl phenylmethyl diester 
• 2094-69-1 benzyl pivalate 
• 34544-98-4 α-Phenylsulfonyl-α-benzoyl-β-phenylaethan 
• 5418-11-1 phenyl styryl sulfone 
• 108-86-1 bromobenzene 
• 5535-48-8 PVS 
• 98-09-9 benzenesulfonyl chloride 
• 100-52-7 benzaldehyde 

Downstream Products

• 81016-05-9 Benzoic acid 1-(1-benzenesulfonyl-2-phenyl-ethyl)-4-oxo-cyclohexa-2,5-dienyl ester 
• 100-42-5 styrene 
• 71-43-2 benzene 
• 676593-26-3 5,5-dimethyl-2-(2-phenylethyl)benzo-1,3,2-dioxaborinate 
• 618-41-7 Benzenesulfinic acid 
• 1134193-11-5 C₂₀H₂₂O₃S 
• 60012-62-6 phenyl-1 hexanol-2 
• 2344-71-0 5-phenylpentan-2-ol 
• 60341-39-1 (E)-4-phenylbut-2-enoic acid 
• 81280-87-7 4-((Z)-1-Benzenesulfonyl-2-phenyl-vinyl)-phenol 
• 6554-98-9 trans-4-Hydroxystilbene 
• 16212-06-9 phenyl styryl sulfone 
• 135295-91-9 C₃₀H₂₇F₃O₅S 
• 135295-99-7 C₂₉H₂₈ 

Relevant articles and documents

Base-Mediated Radical Borylation of Alkyl Sulfones

A practical and direct method was developed for the production of versatile alkyl boronate esters via transition metal-free borylation of primary and secondary alkyl sulfones. The key to the success of the strategy is the use of bis(neopentyl glycolato) diboron (B2neop2), with a stoichiometric amount of base as a promoter. The practicality and industrial potential of this protocol are highlighted by its wide functional group tolerance, the late-stage modification of complex compounds, no need for further transesterification, and operational simplicity. Radical clock, radical trap experiments, and EPR studies were conducted which show that the borylation process involves radical intermediates.

Visible- And UV-Light-Induced Decarboxylative Radical Reactions of Benzoic Acids Using Organic Photoredox Catalysts

Photoinduced decarboxylative radical reactions of benzoic acids with electron-deficient alkenes, diborane, and acetonitrile under organic photoredox catalysis conditions and mild heating afforded adducts, arylboronate esters, and the reduction product, respectively. The reaction is thought to involve single-electron transfer promoted the generation of aryl radicals via decarboxylation. A diverse range of benzoic acids were found to be suitable substrates for this photoreaction. Only our two-molecule organic photoredox system can work well for the direct photoinduced decarboxylation of benzoic acids.

Green Organocatalytic Oxidation of Sulfides to Sulfoxides and Sulfones

A highly efficient synthetic methodology towards the selective synthesis of sulfoxides and sulfones is reported using a cheap and green organocatalytic method. Starting from sulfides and using 2,2,2-trifluoroacetophenone as the organocatalyst and H2O2 as the oxidant, the high-yielding preparation of sulfoxides or sulfones is described, being dependent on the reaction conditions.