284043-22-7

Basic information

• Product Name: p-(ethoxycarbonyl)phenylselenotrimethylstannane
• CAS NO: 284043-22-7
• Molecular Weight: 391.944
• Mol File: 284043-22-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: p-(ethoxycarbonyl)phenylselenotrimethylstannane(CAS DataBase Reference)
• NIST Chemistry Reference: p-(ethoxycarbonyl)phenylselenotrimethylstannane(284043-22-7)
• EPA Substance Registry System: p-(ethoxycarbonyl)phenylselenotrimethylstannane(284043-22-7)

Safety Data

• Hazardous Substances Data: 284043-22-7(Hazardous Substances Data)

Upstream product

• 1066-45-1 trimethyltin(IV)chloride 
• 181075-86-5 bis(p-(ethoxycarbonyl)phenyl)diselenide 

Downstream Products

• 420-60-0 trimethyltin fluoride 
• 181075-89-8 (E)-3-[(p-ethoxycarbonyl)phenylseleno]-4-fluorohex-3-ene 

Relevant articles and documents

Reactions of RSe-EMe3 (E = Si, Ge, Sn, Pb) with XeF2 - RSe-F equivalents in the fluoroselenenylation of acetylenes

Selenides of the type R1Se-EMe3 (E = Si, Ge, Sn, Pb) react with xenon difluoride by cleavage of the Se-E bond to yield the R1Se-F intermediate and the fluorides Me3E-F, whereas the Se-C bond in PhSe-tBu (E = C) is stable against XeF2. The presence of R1Se-F intermediates is confirmed by addition to acetylenes (4-octyne, 3-hexyne). Thus, the fluoroselenenylation of acetylenes gives fluoro(organylseleno)olefins in preparative yields. In the cases of E = Si, Ge, Sn, and Pb, aryl and n-alkyl groups are suitable as the substituent R1. The X-ray crystal structural analysis of (E)-3-(p- carboxyphenylseleno)-4-fluorohex-3-ene - the first example of an uncharged fluoroselenoolefin synthesized from p-EtO2C-C6H4-Se-SnMe3, XeF2, and 3- hexyne followed by an ester hydrolysis - shows that the addition of the selenenylfluoride intermediate to the acetylene proceeds via a trans- addition, as is known for the R2Se2-XeF2 reagents.