2845-91-2

Basic information

• Product Name: Benzenemethanol, 2-methyl-a-(2-methylphenyl)-
• Synonyms: Hydroxy-di-o-tolyl-methan;2,2'-Dimethyl-benzhydrol
• CAS NO: 2845-91-2
• Molecular Formula: C15H16O
• Molecular Weight: 212.291
• Mol File: 2845-91-2.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 2-methyl-a-(2-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2-methyl-a-(2-methylphenyl)-(2845-91-2)
• EPA Substance Registry System: Benzenemethanol, 2-methyl-a-(2-methylphenyl)-(2845-91-2)

Safety Data

• Hazardous Substances Data: 2845-91-2(Hazardous Substances Data)

Upstream product

• 932-31-0 ortho-tolylmagnesium bromide 
• 87-24-1 ethyl 2-methylbenzoate 
• 16419-60-6 2-Methylphenylboronic acid 
• 529-20-4 2-methylphenyl aldehyde 
• 95-46-5 2-methylphenyl bromide 
• 109-94-4 formic acid ethyl ester 
• 107-31-3 Methyl formate 
• 60973-61-7 2,2'-dimethyl-benzhydryl chloride 
• 71-43-2 benzene 
• 60-29-7 diethyl ether 
• 1018-97-9 2,2'-dimethylbenzophenone 
• 6699-93-0 (2-methylphenyl)lithium 
• 1113-49-1 2-methylalanine ethyl ester 

Downstream Products

• 1018-97-9 2,2'-dimethylbenzophenone 
• 74563-04-5 bis(2-phenylprop-2-yl)ether 
• 84988-01-2 bis(2-methylphenyl)methylium 
• 1356835-88-5 2-(bis(2-methylphenyl)methyl)-2-methyl-1H-indene-1,3(2H)-dione 
• 1356835-91-0 C₂₅H₂₆O₂ 
• 116296-33-4 2,2’-bis(2-(methyl)phenyl)acetonitrile 
• 86846-62-0 (2,2'-Dimethyldiphenylmethyl)lithium 
• 1620963-16-7 (4R,5R)-3-benzyl-4,5-di(tert-butyl)-1-(bis(2-methylphenyl)methyl)imidazolidinium chloride 

Relevant articles and documents

Efficient Suppression of Chain Transfer and Branching via Cs-Type Shielding in a Neutral Nickel(II) Catalyst

An effective shielding of both apical positions of a neutral NiII active site is achieved by dibenzosuberyl groups, both attached via the same donors’ N-aryl group in a Cs-type arrangement. The key aniline building block is accessibl

Photo-induced phosphorus radical involved semipinacol rearrangement reaction: Highly synthesis of γ-oxo-phosphonates

Hydroxyphosphoric acids display the unique biological activities, and they have some attractive prospects as clinical drug moleculars. Herein, a new approach for the synthesis of γ-oxo-phosphonates (the precursor of hydroxyphosphoric acid) has been established through the semipinacol rearrangement tactic involved the photo-induced phosphorus radical process. Most important, this transformation is avoid of the external oxidants, and occurs very well under the sunlight irradiation, meanwhile the γ-oxo-phosphonate was easily derivatized to obtain γ-hydroxyphosphoric acid, thus highlights the synthesis value of this method.

[Ir(COD)Cl]2/tris(2,4-di-t-butylphenyl)phosphite-catalyzed addition reactions of arylboronic acids with aldehydes

[Ir(COD)Cl]2/tris(2,4-di-t-butylphenyl)phosphite-catalyzed addition reactions of arylboronic acids with aldehydes were described. The Ir(I) catalyst, generated from [Ir(COD)Cl]2 and tris(2,4-di-t-butylphenyl)phosphite, was an efficient catalyst system for the addition reactions of a variety of arylboronic acids with aromatic and aliphatic aldehydes. The easy availability of the catalyst and good yields make these reactions potentially useful in organic synthesis.