286-44-2Relevant articles and documents
Direct and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids
Ma, Zhiwei,Zhou, Zhe,Kürti, László
supporting information, p. 9886 - 9890 (2017/08/08)
A RhII-catalyzed direct and stereospecific N-H- and N-alkyl aziridination of olefins is reported that uses hydroxylamine-O-sulfonic acids as inexpensive, readily available, and nitro group-free aminating reagents. Unactivated olefins, featuring a wide range of functional groups, are converted into the corresponding N-H or N-alkyl aziridines in good to excellent yields. This operationally simple, scalable transformation proceeds efficiently at ambient temperature and is tolerant towards oxygen and trace moisture.
The reduction of beta-iodo azides. A stereospecific synthesis of aziridines.
Hassner,Matthews,Fowler
, p. 5046 - 5054 (2007/10/04)
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