290348-16-2

Basic information

• Product Name: 2,2'-(1,4-phenylene)bis[4-(tert-butyl)thiazole-5-carbaldehyde]
• Synonyms: 2,2'-(1,4-phenylene)bis[4-(tert-butyl)thiazole-5-carbaldehyde]
• CAS NO: 290348-16-2
• Molecular Weight: 412.577
• Mol File: 290348-16-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2'-(1,4-phenylene)bis[4-(tert-butyl)thiazole-5-carbaldehyde](CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-(1,4-phenylene)bis[4-(tert-butyl)thiazole-5-carbaldehyde](290348-16-2)
• EPA Substance Registry System: 2,2'-(1,4-phenylene)bis[4-(tert-butyl)thiazole-5-carbaldehyde](290348-16-2)

Safety Data

• Hazardous Substances Data: 290348-16-2(Hazardous Substances Data)

Upstream product

• 4394-85-8 4-morpholinecarboxaldehyde 
• 290348-17-3 2,2'-(1,4-phenylene)bis[4-(tert-butyl)thiazole] 
• 5469-26-1 1-Bromopinacolon 
• 13363-51-4 benzene-1,4-dithiocarboxamide 

Relevant articles and documents

Syntheses of thiazole-containing macroheterocycles related to porphycene

The syntheses of 2,2'-bithiazole-containing and related expanded macrocycles 13-16 were accomplished by the McMurry coupling reaction of the corresponding [2,2'-bithiazole]-5,5'-dicarbaldehyde 6c and 2,2'-(1,4- phenylene)bis[thiazole-5-carbaldehyde] 7, readily available by a two-step reaction sequence. The success of the dimerization strongly depends on the steric repulsion of the substituents vicinal to the CHO group.